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Документ Rational conditions of fatty acids obtaining by soapstock treatment with sulfuric acid(PC Тесhnology сеntеr, 2021) Sytnik, Natalia; Kunitsia, Ekaterina; Mazaeva, Viktoria; Kalyna, Viktoriia; Chernukha, Andrii; Vazhynskyi, Serhii; Yashchenko, Oleksandr; Maliarov, Murat; Bogatov, Oleg; Bolibrukh, BorysAs a result of alkaline neutralization of oils, a significant amount of soapstock is formed, the utilization of which creates an environmental and economic problem. The production of fatty acids from soapstock using sulfuric acid decomposition is investigated in this work. The peculiarity of the work is the determination of regression dependences of the yield and neutralization number of fatty acids on the soapstock processing conditions: temperature and duration. Soapstock obtained after neutralization of sunflower oil was used as raw material. Soapstock indicators: mass fraction of moisture – 15.4 %, total fat – 71.9 %, fatty acids – 64.5 %, neutral fat – 7.4 %. Rational conditions of soapstock processing are determined: temperature (90–95) °С, duration 40 min. Under these conditions, the fatty acid yield is 79.0 %, the neutralization number is 180.0 mg KOH/g. Quality indicators of the obtained fatty acids: mass fraction of moisture and volatile substances – 1.8 %, mass fraction of total fat – 97.0 %, cleavage depth – 64.5 % of oleic acid, the presence of mineral acids – no. Fatty acids correspond to fatty acids of the first grade according to DSTU 4860 (CAS 61788-66-7). An increase in the temperature and duration of soapstock contact with sulfuric acid increases the yield and neutralization number of fatty acids. This is due to a decrease in the viscosity of the reaction medium, an increase in the depth of cleavage of soapstock soaps with sulfuric acid, an increase in the intensity and duration of mass transfer. The developed rational conditions allow obtaining fatty acids from soapstock, which correspond in composition to fatty acids from refined deodorized sunflower oil. The results allow solving a number of economic and environmental problems associated with soapstock utilization and can be implemented in oil refineries and fatty acid production.Документ Establishing rational conditions for obtaining potassium glycerate(PC Тесhnology сеntеr, 2021) Sytnik, Natalia; Kunitsia, Ekaterina; Mazaeva, Viktoria; Chernukha, Anton; Ostapov, Kostiantyn; Borodych, Pavlo; Mazurenko, Valerii; Kovalov, Oleksandr; Velma, Victoria; Kolokolov, VitaliiThis paper reports a study into the dependence of efficient glycerate potassium production involving glycerin and potassium hydroxide solution on the process conditions. The concentration of potassium glycerate in the resulting product has been used as a parameter of the efficient glycerate potassium production process. Glycerates of metals are applied to produce articles in the construction industry, electronics, medicine; they are employed as transesterification catalysts to obtain special fats for various purposes, as well as biodiesel fuel. In order to derive potassium glycerate, heating was applied while agitating a mixture of glycerin and potassium hydroxide. The analysis of potassium hydroxide was performed, in which the basic substance mass fraction was 85.5 %, the mass fraction of carbonate potassium – 0.9 %. The p.a.-grade glycerin was applied in this work, whose basic substance mass fraction was 99.5 %. The effect of the heating temperature of the reaction mixture on the concentration of potassium glycerate in the product has been determined. It has been shown that the rational heating temperature is 145 °C. The dependence of potassium glycerate concentration in the resulting product on the following conditions of the process has been established: a change in the molar concentration of glycerin and a reaction mixture heating duration. Such rational conditions for obtaining potassium glycerate have been defined as a molar concentration of glycerin of 60 % and a heating duration of 4 hours. The experimentally established concentration of potassium glycerate in the product under these conditions was 75.77 %. For potassium glycerate, the melting point (69 °C) and the mass fraction of moisture (0.8 %) have been determined. The results of experimental studies would make it possible to obtain potassium glycerate directly at enterprises where the glycerates of metals are used, from available raw materials, under rational conditions. The defined conditions for obtaining potassium glycerate could make it possible to efficiently utilize material and energy resources.Документ Rational parameters of waxes obtaining from oil winterization waste(PC Тесhnology сеntеr, 2020) Sytnik, Natalia; Kunitsia, Ekaterina; Mazaeva, Viktoria; Chernukha, Anton; Kovalov, Pavlo; Grigorenko, Natalia; Gornostal, Stella; Yermakova, Olena; Pavlunko, Mykola; Kravtsov, MikhailProduction of waxes from spent perlite, which is a waste of sunflower oil winterization, is studied. Winterization is characterized by significant losses of oil with filter powders, and waste utilization is an environmental and economic problem. At the same time, winterization waste contains valuable components – wax and oil, which can be used in different ways. The content of waxes in spent perlite using hexane (18 %), as well as the quality indicators of the obtained wax: melting point 70 °C, saponification number 115 mg KOH/g, acid number 2.6 mg KOH/g, mass fraction of moisture 0,82 % are determined. Spent perlite was treated with a solution of sodium chloride during boiling, settling of the obtained mass, washing and drying of wax. The dependence of the yield and melting point of the extracted waxes on the processing parameters: the concentration of sodium chloride solution, temperature and duration of settling is found. Rational conditions for spent perlite processing are determined: the concentration of sodium chloride solution – 7.5 %, settling temperature – 20 °C, settling duration ‑ 10 hours. The experimentally determined wax yield at this point is 14.3 %. Quality indicators of the wax sample obtained under rational conditions are studied: melting point 68 °С, saponification number 110 mg KOH/g, acid number 2.8 mg KOH/g, mass fraction of moisture 0.85 %. These values correlate with the data for wax extracted using hexane, as well as with reference data on the quality of beeswax and sunflower wax. The data obtained allow recycling spent perlite without organic solvents, which makes the process more environmentally friendly and cost-effective, as well as solves environmental problems associated with the utilization of winterization waste.Публікація Determination of the influence of natural antioxidant concentrations on the shelf life of sunflower oil(PC Тесhnology сеntеr, 2020) Sytnik, Natalia; Kunitsia, Ekaterina; Mazaeva, Viktoria; Chernukha, Anton; Bezuglov, Oleg; Bogatov, Oleg; Beliuchenko, Dmytr; Maksymov, Andrii; Popov, Mykola; Novik, I. O.The influence of natural antioxidants from different types of vegetable raw materials on the processes of oxidative and hydrolytic spoilage of sunflower oil during storage is studied. Plant antioxidants are more environmentally friendly and safer than synthetic ones. Green tea leaves and oak bark were used as vegetable raw materials. Water-ethanol extracts from vegetable raw materials were added to oil samples in experimental concentrations. The samples were stored in the laboratory conditions at the temperature of (20±2) °C. The study was performed for 5 months. The values of the acid and peroxide numbers were determined. The most effective blend of antioxidants showed the increase in the acid number from 0.12 to 0.20 mg KOH/g (concentration of green tea extract – 0.05 %, without the addition of oak bark extract). According to the values of the peroxide number, the most effective blends of antioxidants were the experiment points with the following green tea extract:oak bark extract ratio: (0.05:0.05) %, (0.025:0.025) %, (0.025:0.05) %, (0.05:0.025) %. To determine the induction period of oil and, accordingly, its shelf life under experimental conditions, the values of the peroxide numbers were used. It is rational to use extractives from oak bark and green tea under the following conditions: the concentration of each of the antioxidant extracts in terms of dry matter – (0.025‑0.04) %. The maximum induction period is 100 days. The efficiency of natural antioxidants in terms of the concentration of oak bark and green tea extracts is 0.05 and 0.025 %, respectively, was compared to the effectiveness of the corresponding concentration of one of the synthetic antioxidants – butylhydroxyanisole. When using butylhydroxyanisole, the induction period of oil was 65 days, and when using natural antioxidants – 74 days.Документ Investigation of the influence of stabilizers on the viscosity of the recovered mixture of a hypertonic drink for athletes(Scientific Route OÜ, Tallin, Estonia, 2020) Bochkarev, Sergiy; Mazaeva, Viktoria; Ovsiannikova, Tetiana; Zviahintseva, OksanaWhen introducing plant and animal protein products, in addition to nutritional value, it is advisable to assess their physicochemical properties and technological indicators, in particular, homogeneity and consistency stability. The aim of research is to determine the effect of consistency stabilizers on the viscosity of reconstituted hypertonic drink for athletes based on flaxseed cake, sesame seeds and whey protein concentrate.The mass fraction of protein in the model dry mixture of a hypertonic drink, as well as in its individual components by the Kjeldahl method, the mass fraction of fiber – by the gravimetric method, the mass fraction of lipids – by the extraction-gravimetric method, the mass fraction of moisture – by the thermogravimetric method. The mass fraction of ash in the mixtures was carried out by the method of incineration followed by calcining the mineral residue at a temperature of 450 ... 600 °C. The effective viscosity in the reduced samples of mixtures without and with the addition of stabilizers was determined on a rotational viscometer "Rheotest 2". For the planning of the experiment and data processing, mathematical methods were applied using the Microsoft Office Excel 2003 software package.The chemical composition of individual components and a model dry mixture of a hypertonic drink for the nutrition of athletes, including the content of compounds that have a stabilizing effect on the restored product, has been investigated. It has been proved that the effective viscosity of the reconstructed model mixture in comparison with the effective viscosity of the individual components of the mixture nonaditively increases. The mutual influence of the consistency stabilizers (gum arabic (E 414) and carboxymethylcellulose (E 466)) on the val-ue of the effective viscosity of the reconstituted hypertonic drink was investigated. The developed model mixture of a hypertonic drink is recommended to be used for the development of competitive dry mixtures of hypertonic drinks of plant and animal origin for the nutrition of athletes.Документ Analysis of the influence of technological parameters of the chlorogenic acid extraction process from sunflower meal on the degree of its extraction(Технологический Центр, 2020) Labeiko, Marina; Gladkiy, Fedir; Bochkarev, Sergiy; Mazaeva, Viktoria; Litvinenko, Olena; Ovsiannikova, Tetiana; Zhyrnova, Svitlana; Sytnik, NataliaThe object of research is the efficiency of extraction of chlorogenic acid ‑ the natural antioxidant, depending on the conditions of its extraction from sunflower meal. The main problem of this issue is the fact that the extraction degree of the specified phenolic compound is influenced by many factors, such as the degree of grinding of the product, the type of raw material, the method of extraction, the nature of the solvent-extractant, the temperature and duration of the extraction process, the hydromodule in the system "raw – extractant" etc. The impact of each of these parameters requires careful consideration and appropriate research. This will determine the optimal values of the specified parameters of the extraction process and increase the efficiency of extraction of chlorogenic acid. In this work, the raw material for the production of chlorogenic acid is a meal made from sunflower seeds – a cheap second raw material of oil and fat production. Previous studies have found that a high-efficiency extractant of the specified antioxidant is a solution of ethyl alcohol with a concentration of 60 %, and the optimum temperature of the process of extracting chlorogenic acid from sunflower meal is the boiling point of the extractant. As a result of this study, the regularity of the influence on the extraction degree of chlorogenic acid of such technological parameters as the hydromodule in the system "meal – ethyl alcohol solution 60 %" (hereinafter referred to as "meal – extractant") and the duration of the extraction process were studied. Experiments to determine the dependence of the extraction degree of chlorogenic acid on the hydromodule in the system "meal – extractant" and the duration of extraction were carried out in accordance with the plan of the full factor experiment. Mathematical methods using the Microsoft Office Excel 2003 (USA) and Stat Soft Statistica v6.0 (USA) software packages have been applied for experiment planning and data processing. The dependence indicated in the paper is a quadratic function that predicts an increase in chlorogenic acid content during extraction, with an increase in the hydromodule in the "meal‑extractant" system from 1:5 to 1:10 and a decrease in the extraction time from 60 minutes up to 30 minutes. It is established that for the maximum possible increase in the extraction degree of chlorogenic acid from the meal of sunflower seeds, the optimal value of the hydromodule extraction ‑ 1:10, the duration of extraction ‑ 30 minutes. The obtained results allow to increase the extraction degree of chlorogenic acid from sunflower meal from 2.46 % to 5.58 %. This indicates the possibility of increasing the efficiency of extraction of antioxidant more than 2 times.Документ Research of oxidative stability of vegetable oils for use in sport nutrition(Технологический центр, 2019) Sytnik, N.; Mazaeva, V.; Bilous, O.; Bukhkalo, S. I.; Glukhykh, V.; Sabadosh, G.; Natarov, V.; Yarmysh, N.; Kravchenko, T.; Zakharkiv, S.Об’єктом дослідження є соняшникова, соняшникова високоолеїнова та ріпакова олії, які є важливими у виробництві продуктів харчування для людей з підвищеними фізичними навантаженнями. Такі продукти мають бути збалансовані за компонентним складом та збагачені біологічно активними речовинами, вітамінами, антиоксидантами. Олії та жири використовують як важливий компонент спортивного харчування. Розповсюдженою олією є соняшникова олія, яка забезпечує раціон лінолевою кислотою, а також ріпакова олія, яка збагачує продукти ліноленовою кислотою. Одним з найбільш проблемних місць використання олій є окиснювальне псування, оскільки це призводить до утворення небезпечних для здоров’я сполук. В ході дослідження використовувалися метод активного кисню та прилад Oxitest (Італія). Перший метод дозволяє безпосередньо оцінювати вміст продуктів окиснення в олії через значення пероксидного числа, другий метод дозволяє вимірювати витрату кисню під час процесів окиснення в олії. Проведено дослідження окиснювальної стабільності олії соняшникової методом активного кисню та методом окиснення з використанням приладу Oxitest за температури 110 °С. Встановлено, що періоди індукції, визначені двома методами, є близькими (2 год. 40 хв. та 2 год. 43 хв., відповідно). Встановлено закономірність зниження періоду індукції олії соняшникової під час підвищення температури методом окиснення на приладі Oxitest. Використано температури 90, 100 та 110 °С. Виконано порівняльне дослідження окиснювальної стабільності соняшникової, соняшникової високоолеїнової та ріпакової олій. На підставі одержаних даних наведено порівняльну характеристику стійкості дослідних олій до окиснення та надано рекомендації для їх використання у спортивному харчуванні. Одержані дані дозволять оцінювати вплив кожної з дослідних олій на строк придатності олієвмісного продукту.