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Документ Identification of the oxidation and hydrolysis products content influence on the rapeseed oil oxidation induction period(Technology center PC, 2024) Stankevych, Serhii; Gorbunov, Kostiantyn; Zabrodina, Inna; Popov, Mykola; Kalyna, Viktoriia; Novozhylova, Tetiana; Falalieieva, Tetiana; Ovsiannikova, Tetiana; Ponomarova, Maryna; Zolotarov, AndriiThe object of the study is the dependence of the induction period of rapeseed oil on the content of oxidation and hydrolysis products. A feature of the work is determining the approximation dependence of the induction period of accelerated oxidation of refined rapeseed oil on the content of primary oxidation products and free fatty acids. This is useful when predicting the shelf life of refined rapeseed oil. It was determined that both factors negatively affect the oxidation stability of refined rapeseed oil. An increase in the peroxide value decreases the induction period of model oil samples by 32.8512 units for each additional mmol ½ O/kg. In turn, increasing the acid value of oil samples reduces the induction period by 19.8424 units for each additional mg KOH/g. Different oxidation dynamics of model samples of refined rapeseed oil with tocopherol were revealed, depending on the concentration of primary oxidation and hydrolysis products. The obtained data are explained by the fact that the primary lipid oxidation products are unstable and quickly decompose to form free radicals. These radicals initiate further lipid oxidation, resulting in reduced oil quality. In addition, free fatty acids are more reactive than triglycerides and are more easily oxidized. A feature of the obtained results is the possibility of modeling processes that affect the oxidation stability of refined rapeseed oil. From a practical point of view, the research results allow initiating measures to maintain the safety of oil-containing food products based on refined rapeseed oil. An applied aspect of using the scientific results is the possibility of rationalizing the storage conditions of refined rapeseed oil to maximize its shelf life and increase competitiveness.Документ Technological aspects of application of the phytosorbent with nanotubes in the process of adsorptive oil purification(Національний технічний університет "Харківський політехнічний інститут", 2021) Krichkovskaya, Lidiya Vasilevna; Essam, Elnaggar; Dubonosov, Vladimir LeonidovichIn the present article importance of adsorptive purification of vegetable oils is shown as the most responsible technological stage. Insufficiency of scientific developments in the scope of domestic sorbents in Ukraine is pointed out. The phytosorbent with nanotubes from sunflower peel improving some quality parameters of non-refined sunflower and soybean oils to standard values for refined oils has been offered. Some literature data on the main characteristics of a number of sorption materials (carbonaceous, natural, fibrous, and sorbents obtained from agricultural waste - Corylus avellana Lambert nuts) as a result of heat treatment are analyzed. The main sorption properties are considered; dignity; limitations. The effect of temperature on the productivity of pyrolysis of plant raw materials and the properties of the resulting carbonizates in the temperature range 150-600 °C was investigated. The duration of exposure of materials at the final temperature of the process in all experiments was the same and amounted to 1 h. Analysis of the experimental data allows us to conclude that temperature is the main factor affecting the process of carbonization of the initial plant material. Regardless of the pyrolysis atmosphere, the yield of the product from plant raw materials decreases with a significant increase in temperature. At present, the main raw material for the industrial production of adsorbents is in many studies organic substances - wood, fossil coal, peat, remnants of the processing of agricultural raw materials due to their low cost and large amount. Solving the problem of creating sorbents based on plant raw materials with the inclusion of hydrated fullerenes in their composition solved the problem of creating sorbents and environmental problems, since the waste did not always find a useful application. Concentration of water solution of hydrated C60, fast C60FWS, є molecular-coloidal systems and spherical fractal clusters, structural unit of which is micro-hydrophilic, high-hydrophilic supramolecular complex, molecules can be folded to fit into ) 24-hydration of fullerene C60 (C60HyFn). The hydrated cultivation is set in its own well-ordered, structurally heterogeneous watery middle, in which the directness and kinetics of chemical processes are seen in such, that it is necessary to be washed in order to clean.