Кафедра "Безпека праці та навколишнього середовища"

Постійне посилання зібрання

https://repository.kpi.kharkov.ua/handle/KhPI-Press/2354

Офіційний сайт кафедри http://web.kpi.kharkov.ua/safetyofliving

Від 2020 року кафедра має назву "Безпека праці та навколишнього середовища", попередня назва – "Охорона праці та навколишнього середовища", первісна назва – кафедра "Охорона праці".

Кафедра "Охорона праці" була створена в 1963 році. Першим її завідувачем був доцент Наумов С. С., який очолював кафедру протягом 1963-1970 років.

За час існування кафедри, крізь її "стіни" пройшло понад 70 тисяч студентів.

Кафедра входить до складу Навчально-наукового інституту механічної інженерії і транспорту Національного технічного університету "Харківський політехнічний інститут".

У складі науково-педагогічного колективу кафедри працюють 25 викладачів, серед яких 2 доктора технічних наук, 17 – кандидатів технічних, біологічних та психологічних наук, 1 – доктор філософії, 3 співробітника мають звання професора, 14 – доцента.

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A Conversation with Prof. Dr. Vambol Sergij
(National Institute of Maritime Affairs (NIMA), Karachi, 2024) Vambol, Sergij
"Dr. Vambol Sergij is a member of the International Advisory Committee for ICASF-2023. He is the head of the Department at Department of Occupational and Environmental Safety and also serves as a Professor at the National Technical University Kharkiv Polytechnic, Ukraine. He has a degree in Mechanical Engineering from 1994. Vambol holds a degree in Doctor of Science in Environment Safety from 2014. In 2015, he received the conferment diploma of the academic degree of Professor in Applied Mechanics. From 2004 onwards, he has been engaged in research and development programs in the field of Environmental Engineering. Vambol has extensive scientific experience and has authored more than 400* scientific and educational publications, including 25 patents and 15 monographs."
Analysis and reflection of the current situation in the field of occupational health and safety management in Сhina construction enterprises
(Харківський національний університет міського господарства ім. О. М. Бекетова, 2023-11-09) Liu, Yujun; Євтушенко, Наталія Сергіївна
With the continuous development and progress of China's economy, people pay more and more attention to safety in the production operation. China has issued a series of laws, regulations, regulations and safety technical standards in road and bridge construction safety production management, and has established a relatively complete organization system of road and bridge construction safety management, and road and bridge construction safety management has also made remarkable achievements. However, the accident frequency is still at a high level in road and bridge construction.
Analysis of a City’s Heat Island Effect on the Micro-Climate Parameters within Cities
(Pakistan Academy of Sciences, 2023) Sharma, Rishabh; Amadur Rahman, Khan; Tyshchenko, Vasyl; Illiash, Oksana; Mezentseva, Iryna
The Urban Heat Island (UHI) is a micro-climatic phenomenon that influences the urban areas by elevating its temperature. UHI not only causes the thermal discomfort but also exert serious health issues along with aggravation of urban microclimate. Although a lot of research has been done on this phenomenon but UHI effect on micro scale is still less explored. This paper attempts to make a contribution in UHI studies of micro-climate. It consists of examination of UHI impact on microclimate of Aligarh city areas using mobile traverse method. This study determined the presence and extent of UHI’s microclimate variation within urban communities of different environmental layout and functional uses. The UHI effect started to appear from early afternoon and continue to rise with maximum UHI intensity recorded at early night. The highest recorded UHI intensity was 3.1 °C (at 21:00 hrs.), and the lowest was 0.6 °C (at 09:00 hrs.). A comparison of two districts of the same city located at a distance of 3 km and differing in population density, the number of buildings and landscaping showed that in the L1 area with more dense population and low landscaping, the temperature was consistently higher during the daily period; also the L1 region had less humidity, which combined with the already high temperature, makes it difficult to breathe and control the microclimate. These findings can be used for consideration for the future sustainable development of the affected area in regard of thermal comfort, environmental health and urban planning.
Analysis of the Sanitary Purification of Gas Emissions from Dust in the Lime Manufacture
(Scientific Route, 2017) Pitak, Inna V.; Briankin, Serhii S.; Pitak, Oleg Ya.; Shaporev, Valery P.
Experimental studies have been carried out to study the effect of the location of the blade vortex from the end of the flue (the flow outflow from the flue to the separation chamber) by the value Vϕmax and the determination of the optimum cross section where Vϕmax is reached, and also the study of the influence of structural changes on the purification efficiency. The dependence of this swirler on the value of the tangential velocity of the gas flow at its exit from the separator is established. The cross-sections of the flue duct in which, after the swirler, the maximum values Vϕ, Vr are reached, the features of the dust-gas flow in the studied sections are considered. Based on the studies of the hydrodynamic situation during the flow of a rotating flow in the flue after the swirler, the possibilities of agglomeration of dust particles in the investigated zones, as well as the destruction of NOx gas impurities, are analyzed. During the operation of the reconstructed vortex dust collector, qualitative indices are attained, which confirm the expediency of the conducted studies and the expediency of reconstructing the vortex apparatus. It is proved that the installation of the blade vortex enhances the purification efficiency of the dust-gas flow in a vortex dust collector and will allow for a comprehensive purification of the exhaust gases.
Analysis of ways reducing drilling waste in oil and gas production influencing on natural environment
(UNIVERSITAS Publishing, Romania, 2019) Shestopalov, Oleksii; Rykusova, N. I.; Tseitlin, Musii; Raiko, Valentina
Approaches to the organization of workplaces in "open space" offices
(Національний технічний університет "Харківський політехнічний інститут", 2019) Hofreiter, Ladislav; Ilinska, Olha
The aspects that should be considered when organizing workplaces in "open space" type offices are considered.
Assessment and prevention of the propagation of carbon monoxide over a working area at ARC welding
(Технологический центр, 2019) Berezutskyi, Viacheslav; Hondak, Inna; Berezutska, Nataliia; Dmitrik, Vitaly; Gorbenko, Veronika; Makarenko, Viktoriia
This paper reports a study of air environment at industrial premises where welding processes take place, with special attention paid to the formation of carbon monoxide (oxide) (CO) in the working environment in the process of manual arc welding. We have given the classification of basic harmful substances generated during welding and related processes in terms of the character of negative influence on the body of a welder. A mathematical model of the dynamics of change in the concentration of carbon monoxide in the air of a working area has been constructed, based on the amount of a harmful substance (m) in the air at premises at a time point, the intensity of its release into air, and the air exchange rate. A given mathematical model includes the propagation of carbon monoxide in the air, considering the air exchange between the overall volume of a premise and the local volumes of working zones. There are not enough studies into the formation of carbon monoxide during welding processes, which is why examining this process is a priority. Out experimental study has confirmed that the concentration of carbon monoxide outside the local volumes of local ventilation devices, that is in the air of working zones, remains constant (to 0.01 mg/m³) and does not exceed MPC (20 mg/m³). A failure or the absence of general ventilation leads to a rapid increase in the concentration of carbon monoxide (CO) in line with an exponential dependence (from 150 to 200 mg/m³ over 0.5-0.6 hours) within a small closed workspace (1 m³), and can quickly spread throughout the entire premise. However, a failure or the absence of general ventilation leads to a rapid increase in the concentration of carbon monoxide (CO) in line with an exponential dependence. This indicates that general ventilation is important, but it does not warrant safety for welders and other workers from gas poisoning. Therefore, the use of local ventilation must be ensured, as well as respiratory protection for all present when conducting welding processes. The derived mathematical models make it possible to assess risks during welders’ operations, to take into consideration CO emissions when calculating ventilation systems in working areas, to adjust the system that manages risks and labor safety
Basics of psychophysiological assurance of the reliability of professional activity and efficiency of a human operator
(2022) Movmyga, N. E.; Maksymenko, O. A.
Technical progress on the modern stage of society development is accompanied by the continuous increase of human role in the achievement of high efficiency and quality of work. Complex mechanization of production processes, control systems automation, the usage of computer engineering, and information models of individual and collective usage radically change labor characteristics. A man performs operator functions, his activities continuously become more complicated despite permanent progress of technique and automation of production processes. Modern control system imposes responsibility both on a man, using technique and on that who ensures efficiency and reliability of this usage. Role of human factor in occupational safety is very great. Psychophysiological features of labor process participants are especially important. Psychophysiological basis of safety is based on psychology and physiology of a man. Psychophysiology of occupational safety is based on such sciences as physiology of labor, engineering psychology, ergonomics, etc. Safety psychology considers the application of psychological knowledge for occupational health safety ensurance and is a key point in the structure of actions aimed at human safe activity. Both, internal and external factors influence on the occurrence of such adverse state as stress, fatigue, and decrease in working capacity. The following external factors may be present at production enterprises: microclimat parameters, light, noise, vibration, the other labor environment, social-psychological climate, management style, etc. The following factors may be considered as internal reasons of adverse functional conditions: nervous system type, temperament, professional skills, etc. The aspect of internal factors which have an impact on the appearance of adverse functional conditions is not well studied nowadays. When hiring an employee and during his adaptation it is necessary to take into consideration his psychological features, as they directly impact success and work speed, his condition. It is necessary to take into account an employee's functional conditions during his work performance. The objective of the metodological instructions "Basis of psychophysiological assurance of professional activity reliability and human operator efficiency" is the formation of theoretical knowledge and practical skills which include holistically interconnected physiological and psychological patterns of employee's professional activity, causing efficiency, reliability and occupational health safety, professional health and longevity increase.
Beginning Microsoft Excel 2010. Part 3
(Kharkiv Petro Vasylenko National Technical University of Agriculture, 2016) Megel, Yu. Ye.; Kovalenko, S. M.; Chaly, I. V.; Mikhnova, E. D.
Methodological guidelines are intended to assist students in studying Informatics in English, both in the classroom and individually.
Certification of workplaces and risks
(ГО "СФБЖДЛ", 2016) Berezutskyi, Viacheslav; Skibniewska, Krystyna; Madieva, Gulmira
At this material were analyzed of conformity to carry out of certification of workplaces by the old regulatory requirements and international standards that are including the maps of risk a workplaces. New approaches to the procedure for certification of workplaces taking into account the requirements of international standards and risk.
Chemical deposition of CdS films from ammoniac-thiourea solutions
(Технологический центр, 2018) Pancheva, Hanna; Khrystych, Olena; Mykhailova, Evgeniia; Ivashchenko, Maryna; Pilipenko, Alexei
This paper investigates the process of chemical deposition of CdS films from ammonia-thiourea solutions. It was established that a change in the turbidity of solution occurs in the process of chemical deposition. The results of visual observations and measurement of turbidity of solution allowed us to establish that these dependences could be used to monitor the status of the process. Visual observations correlate with the obtained dependences for turbidity and suggest that the chemical deposition of CdS includes the accumulation of colloidal-dispersed precipitate in the volume of solution, agglomeration of CdS particles, and a stationary mode of the CdS film growth at the surface of a sample. The first stage of the process is matched by a sharp increase in the turbidity of solution; the second stage is accompanied by the emergence of a maximum in the dependence. No significant change in turbidity occurs at the third stage. The observation of morphology of the resulting precipitate allowed us to establish working concentrations of reagents in solution, which ensure obtaining a high-quality CdS film with a thickness not less than 100 μm. The working concentrations of cadmium chloride, ammonia, and thiourea are, respectively, 1.8, 0.6, and 8.4 g·l⁻¹. It was assumed that the CdS formation is accompanied by the formation of thiourea. This is confirmed by data on the analysis of a working solution. An analysis of the solution revealed high concentrations of the CO₃²⁻ ions, which are a product of the thiourea decomposition. The data obtained are a preliminary stage in the development of a technology of chemical deposition of CdS films from ammonia-thiourea solutions.
Construction of a generalized model of the harmful substances biochemical destruction process kinetics under conditions of substrate inhibition using the methods of simulation modeling
(Технологический центр, 2019) Bakharievа, Ganna; Falalieieva, Tetiana; Petrov, Serhii; Mezentseva, Iryna; Kobylianskyi, Borys; Tolkunov, Ihor; Bondarenko, Oleksandr
For the purpose of obtaining the complete range of solutions for substrate inhibition of varying intensity, the mechanism of enzyme kinetics in a biocell was modeled by a multi-channel queuing system. A full range of solutions is required to make a well-grounded choice of a unified generalizing formula. The process of biodegradation with substrate inhibition was described mathematically using the method of dynamics of averages. For specific destruction rate, a full range of solutions Vn of the system from minimum n=2 to limiting n→∞ order was found. It was established that the parameters of the curve shape for the solution with minimum inhibition intensity V2 substantially stand out from the general series of the spectrum formulas. The value of the coordinate of function maximum (n=2) V2 is by 1.42 times higher than that of dependence (n=3) V3. In the numerical experiment, the physical test was simulated by description with the help of the method of the least squares of the data, assigned by the calculation from the formulas of different structures, bearing in mind a sporadic random error. The series of numerical experiments demonstrated the capability of the formula of limiting order formula Ve to describe the dependences of the whole spectrum of solutions. During describing the intermediate ratio V3 with the help of formulas V2 and Ve, the benefit is the possible range of changing the concentrations, which is by 1.5-2 times larger at the same relative error for dependence Vе. For critical minimal order, an average relative error is sure not to exceed five percent. An increase in random error always result in statistical equality, in accuracy of describing by formulas of minimal V2 and limiting orders Ve of the data, assigned by calculation of second-order dependences. Statistical equality is achieved at the ratio of a random error to the initial error equal to ≥2.4. Collectively, the importance of the results of numerical modeling of a physical experiment involves proving the possibility of using the formula of limiting order Ve as unified when describing the biodegradation processes with different mechanisms of substrate inhibition. This conclusion is proved by the adequate (R2=0.9396-0.9953) description with the help of the dependence of limiting order of experimental data on five harmful substances with varying inhibition degrees. A large amount of calculation allowed achieving a definite result – we obtained the unified formula that makes it possible to proceed to scientifically grounded design calculations for bio-treatment plants.
Creation of a safe educational environment for ukrainian youth during war conditions
(Ха́рківський націона́льний педагогі́чний університе́т імені Григорія Сковороди, 2024) Tverdokhliebova, Natalia; Yevtushenko, Nataliіa
The migration processes in Ukraine have become especially intense in recent years. On the one hand, they are a serious challenge for the education of young people, but, on the other hand, they represent an opportunity for their development, although they require legal support and regulation. The purpose of this article is to study the main psychological reactions to life threatening situations that can affect the psychological well-being of children and youth under martial law in order to develop recommendations for overcoming stress in the process of adaptation to new conditions of existence in a new country and integration into a new educational environment.
Determination of fat-soluble dyes influence on the oxidation induction period of their oil solutions
(PC Тесhnology сеntеr, 2023) Petik, Pavlo; Stankevych, Serhii; Zabrodina, Inna; Zhulinska, Oksana; Mezentseva, Iryna; Haliasnyi, Ivan; Hontar, Tatyana; Shubina, Lidiia; Kotliar, Oleh; Bondarenko, Svitlana
The object of the study is the period of induction of accelerated oxidation of oil solutions of fat-soluble dyes chlorophyll and beta-carotene. The effect of the content of fat-soluble dyes on the period of induction of accelerated oxidation of their solutions in refined sunflower oil was studied. The peculiarity of the work consists in establishing approximate graphic and mathematical dependences of the term of the induction period of accelerated oxidation of refined sunflower oil on the content of chlorophyll and beta-carotene separately and together. This is important for predicting the shelf life of oil solutions of fat-soluble dyes. It was determined that chlorophyll A practically does not show a pro-oxidant effect if its content is up to 0.05 g/l. The content of chlorophyll A at the level of 0.10 g/l leads to a reduction in the duration of the induction period by 14 %; 0.20 g/l – by 36 %; 0.30 g/l – by 48 %. The content of beta-carotene at the level of 0.10 g/l leads to an increase in the duration of the induction period by 35 %; 0.20 g/l – by 47 %; 0.30 g/l – by 54 %. The content in the oil system of 0.10 g/l of beta-carotene and 0.05 g/l of chlorophyll A leads to a reduction in the period of induction of accelerated oxidation by 8.4 % compared to the oil solution of 0.10 g/l of beta-carotene without chlorophyll A. The obtained data are explained by the fact that there is a compensatory effect of the antioxidant beta-carotene on the pro-oxidant effect of chlorophyll A in the oil solution. A feature of the obtained results is the possibility of predicting the shelf life of oil solutions of fat-soluble dyes. From a practical point of view, the results of the research allow to develop oil systems taking into account the separate and compatible features of reactivity to the oxidation of chlorophyll and beta-carotene. An applied aspect of using the scientific result is the possibility of expanding the assortment of oil products of increased nutritional value with different contents of chlorophyll and beta-carotene.
Determination of requirements for protection of radio-electronic means of security management of particularly important state energy facilities from the destructive impact of electromagnetic
(EverScience Publications, India, 2020) Akimov, Oleksandr; Karpa, Marta; Dubych, Clavdia; Zayats, Diana; Movmyga, Nataliia; Tverdokhliebova, Natalia
The article considers the issues of protection of electronic means from the destructive effects of electromagnetic radiation created by terrorist means of electromagnetic effects. The basic requirements to means of protection which are realized on the basis of use of nature-like technologies are defined. Possible variants of influence on radio electronic means (REM) are considered. Requirements for means of protection of electronic means against destructive electromagnetic influence created by terrorist means are defined. The necessity of protection of REM of especially important state objects from the destructive electromagnetic influence created by terrorist means by means of means of protection on the basis of use of the nature-like technologies is proved.
Determining the dynamics of carbon monoxide formation during gas welding processes
(Технологічний центр, 2021) Berezutskyi, Viacheslav; Khondak, Inna; Berezutska, Nataliia
This paper reports a study of the air medium where welding processes take place, with special attention paid to the evolution of carbon monoxide (CO) in the working medium in the process of gas welding. Plots were constructed and polynomial dependences were obtained to show a change in the concentration of carbon monoxide in the air of the working area during gas welding. It was confirmed experimentally that the concentration of carbon monoxide exceeds the permissible sanitary and hygienic indicators MPC (20 mg/m3) during gas welding. As a result of the experiment, the effectiveness of the use of an additional device was proven, namely an umbrella gas concentrator, in order to capture welding gases that are formed during gas welding. It was established that the MPC is exceeded under certain working conditions and welding wire. The carbon monoxide formation during gas welding was analyzed; these processes were compared with electric arc welding. The mathematical dependences derived make it possible to assess the risks of the welders’ work and conclude that the electric arc welding is characterized by a much higher rate of CO evolution from the beginning of the welding process (8.5 mg/s), that speed then decreases over 20 s by 2 times (to 4.5 mg/s). In 90 s, the speed becomes constant, to 2 mg/s. In comparison, gas welding has almost the same rate of CO formation, namely 0.3–0.9 mg/s. By changing the types of welding wires used in gas welding and taking into consideration the type of material that needs to be welded (including the period of its use), it is possible to influence the volume of CO emissions entering the working area and an employee’s respiratory area.
Determining the effect of multifunctional partitions on noise level at "open space" offices
(Технологический центр, 2019) Berezutskyi, Viacheslav; Ilinska, Olha; Vaskovets, Ludmila; Mezentseva, Iryna; Khalil, Viktoriya
Multifunction partitions and their influence on noise levels were explored. It was emphasized that the existing systems of classification of building partitions explore them based on the convenience of their use, material, design, etc. At the same time, not enough attention was paid to their impact on the indicators of a decrease in noise levels in office premises. Partitions are made of different materials, having different properties; they are different in shape and enclosure of premises or workspace at different distances from the floor. In such cases, there arises a complicated problem of selecting certain types of partitions, which, as shown in the research, make it possible to solve the problem of optimizing working conditions and reduce the negative effect of noise on the health of employees. The performed research showed that the set problem of noise reduction through the use of partitions can be solved. The factors that should be especially taken into consideration include the height of a partition (degree of enclosure of the height of premises by a partition), material of partitions, existence of technological openings and the geometry of their location. It was revealed that double-layer walls, made of heavy materials (density ≈2,500 kg/m3) and 100 % premises enclosure by height, can reduce the noise level by 2-3 times (from 90 dBA to 30-45 dBA). Glass partitions (glass pipes) of moderate heaviness (≈1,200 kg/m3) reduce noise by 1.5-1.6 times. If enclosure of premises is not complete or there are openings, ventilation shafts, etc., the effect of influence of partitions decreases considerably, reducing it almost to zero. Significant influence of partitions takes place in the frequency range of 200-3,000 Hz at noise level of 40-60 dBA. Noise was explored in the premises of the "Open space" type, where various options of partitions were applied (glass pipes in metal casings, ceramic panels, foam plastic panels). The research found that partitions can have a significant impact on noise indicators, but only on condition of complete enclosure of premises by height, closed doors and construction channels in walls. It was established that the material of partitions does not affect noise indicators if the degree of premises enclosure is not complete (less than 100 %). The studies proved the relevance of scientific substantiation of partitions’ application and of determining the relations of premises enclosure with the factors that affect employees with a view to improving their working conditions. Improvement of working conditions, in turn, will make it possible to decrease professional diseases, minimize turnover, and increase work efficiency.
Development of a technology for the production of germinated flaxseed using plasma-chemically activated aqueous solutions
(PC Тесhnology сеntеr, 2023) Kovaliova, Olena; Vasylieva, Natalia; Stankevych, Serhii; Zabrodina, Inna; Mandych, Oleksandra; Hontar, Tatyana; Haliasnyi, Ivan; Kotliar, Oleh; Yanchyk, Oleksandr; Bogatov, Oleg
The result of the research is the development of a technology for the production of germinated flaxseed using plasma-chemically activated aqueous solutions. The object of research was flaxseed. An urgent technological problem is the intensification of the bioactivation process of flaxseed and its effective disinfection. The expediency of using plasma-chemically activated aqueous solutions as an intensifier of the process of flaxseed germination and an effective disinfectant of food raw materials was experimentally proven. It is shown that the use of plasma-chemical activation of process solutions not only accelerates flaxseed germination, but also contributes to a more active accumulation of biologically valuable components in flax raw materials. The composition of flaxseed as a raw material derivative was analyzed. Germinated flaxseed, which is considered a high-value component of food products, was studied separately. An increase in the moisture content of flaxseed during the soaking process by 0.7–1.7 % was recorded. Seedling development increases by 2–9 mm. The germination energy and capacity increase by 5–12 %. The biomass of germinated seeds increases by 39–56 %. In the process of germination, the content of proteins in flaxseed increases from 21.88 to 23.71 %, reducing sugars from 2.37 to 4.02 %. The total content of amino acids increases from 3.64 to 10.38 % compared to the control, and 10 times compared to the raw material. A significant accumulation of vitamins was noted: B1, B2, B3, B5, B6, B7, B9, C, E. In addition, plasma-chemically activated solutions effectively disinfect germinated flaxseed. The technology can be applied in the production of enrichment components of food products. The developed technology will receive special attention in the production of functional food products
Development of rational technology for sodium glyceroxide obtaining
(Технологічний центр, 2022) Korchak, Mykola; Bliznjuk, O. N.; Nekrasov, Serhii; Gavrish, Tatiana; Petrova, Olena; Shevchuk, Natalia; Strikha, Liudmyla; Kostyrkin, Oleg; Semenov, Evgeny; Saveliev, Dmytro
The process of sodium glyceroxide obtaining by the reaction of glycerol and sodium hydroxide in the form of an aqueous solution was investigated. Glycerol salts (metal glyceroxides) are important components in the synthesis of many compounds. Glyceroxides are used in the chemical industry, construction, medical practice, etc. Glyceroxides of alkali metals are used in the production of modified fats and biodiesel fuel. P.a.-grade glycerol (CAS Number 56-81-5) was used with a mass fraction of the main substance of 99.5 %. The parameters of sodium hydroxide (CAS Number 1310-73-2) were studied: the mass fraction of the main substance is 98.0 %, the mass fraction of sodium carbonate is 0.5%. Rational conditions for sodium glyceroxide obtaining were determined: temperature (145 °C) and concentration of sodium hydroxide solution (65 %). Under these conditions, the mass fraction of the main substance in the product was 80 %. The melting point (72 °C) and mass fraction of moisture (0.3 %) in sodium glyceroxide were determined. The catalytic activity of the product in the process of transesterification of palm olein was tested. The increase in the melting point of palm olein was 15 °C. Under similar conditions of using potassium glyceroxide with a mass fraction of the main substance of 75.77 %, the increase in the melting point is 12.1 °C. This indicates an increase in the efficiency of the transesterification process using sodium glyceroxide obtained by the developed technology. The research results make it possible to produce sodium glyceroxide under rational conditions with a high mass fraction of the main substance at enterprises that use metal glyceroxides as a production component or commercial product. The determined rational conditions will make it possible to effectively use the company’s resources and predict the quality of the final product. Досліджено процес одержання натрій гліцерату шляхом реагування гліцерину та натрій гідроксиду у вигляді водного розчину. Солі гліцерину (гліцерати металів) є важливими складовими у процесах синтезу багатьох сполук. Гліцерати застосовуються у хімічній промисловості, будівництві, медичній практиці тощо. Гліцерати лужних металів використовуються у виробництві модифікованих жирів та біодизельного пального. Застосовано гліцерин (CAS Number 56-81-5) кваліфікації ч. д. а. з масовою часткою основної речовини 99,5 %. Досліджено показники натрій гідроксиду (CAS Number 1310-73-2): масова частка основної речовини – 98,0 %, масова частка натрій карбонату – 0,5 %. Встановлено раціональні умови отримання натрій гліцерату: температуру (145 °C) та концентрацію розчину натрій гідроксиду (65 %). За цих умов масова частка основної речовини в продукті склала 80 %. В натрій гліцераті визначено температуру плавлення (72 °C) та масову частку вологи (0,3 %). Перевірено каталітичну активність продукту у процесі переетерифікування олеїну пальмового. Підвищення температури плавлення олеїну пальмового склало 15 °C. За аналогічних умов використання калій гліцерату з масовою часткою основної речовини 75,77 % підвищення температури плавлення становить 12,1 °C. Це свідчить про підвищення ефективності процесу переетерифікування з використанням натрій гліцерату, отриманого за розробленою технологією. Результати досліджень дають можливість виробляти натрій гліцерат за раціональних умов з високою масовою часткою основної речовини на підприємствах, де використовують гліцерати металів як складову виробництва або товарний продукт. Встановлені раціональні умови дозволять ефективно використовувати ресурси підприємства та прогнозувати якість кінцевого продукту.
Development of safe technology of obtaining fatty acid monoglycerides using a new catalyst
(ПП "Технологічний Центр", 2022) Bliznjuk, O. N.; Masalitina, N. Yu.; Mezentseva, Iryna; Novozhylova, Tetiana; Korchak, Mykola; Haliasnyi, Ivan; Gavrish, Tatiana; Fomina, Iryna; Khalil, Viktoriya; Nikitchenko, Olga
Fatty acid monoglycerides are a valuable component of the products of various industries. The emulsifying ability of monoglycerides is used in cosmetic, pharmaceutical, and food production. The process of fatty acid monoglycerides obtaining by the reaction of vegetable hydrogenated fat (salomas) with glycerol (glycerolysis method) has been studied. Potassium glycerate is used as a catalyst, which is characterized by high efficiency and safety of production and use. A feature of the work is the study of the dependence of the yield and melting point of monoglycerides on the technological parameters of glycerolysis. As a raw material, hydrogenated refined fat according to DSTU 5040 (CAS Number 68334-28-1) was used: melting point – 48 °C, mass fraction of moisture and volatile substances – 0.08 %, acid value – 0.25 mg KOH/g, peroxide value – 2.8 ½ O mmol/kg. In all experiments, the glycerolysis temperature was 180 °C, the catalyst concentration – 0.5 % in terms of metal. Rational conditions for glycerolysis were determined: duration (90 min.) and glycerol concentration (50 %). Under these conditions, the monoglycerides yield was 32.9 %, melting point – 61.5 °C. The mass fraction of free glycerol in monoglycerides was 1.0 %, acid value – 2.2 mg KOH/g. The efficiency of monoglycerides obtaining using potassium hydroxide and glycerol mixture as a catalyst under certain rational conditions has been studied. The monoglycerides yield of 30.1 %, melting point of 59 °C were obtained. Therefore, the use of potassium glycerate catalyst is more efficient. The results of the study make it possible to improve the technology for the production of fatty acid monoglycerides using a new catalyst and use resources rationally.

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