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Title: | Methanolysis of N-acetoxy-N-n-propyloxy-N’,N’-dimethylurea in different conditions |
Authors: | Shtamburg, V. G. Tsygankov, A. V. Shtamburg, V. V. Anishchenko, A. A. Mazepa, A. V. Kostyanovsky, R. G. |
Keywords: | nucleophilic substitution; nitrogen; N-acyloxy-N-alkoxyureas; N,N-dialkoxyureas; methanolysis |
Issue Date: | 2014 |
Publisher: | Deuton-X Ltd. |
Citation: | Methanolysis of N-acetoxy-N-n-propyloxy-N’,N’-dimethylurea in different conditions / V. G. Shtamburg [et al.] // European Chemical Bulletin. – 2014. – Vol. 3, № 9. – P. 869-872. |
Abstract: | The methanolysis of N-acetoxy-N-n-propyloxy-N’,N’-dimethylurea in the presence of strong acids at room temperatures or in the boiling methanol yields N,N-dimethoxy-N’,N’-dimethylurea as final product. Primarily the nucleophilic substitution acetoxy group at nitrogen on methoxy group arises. At second stage the transesterification of N,N-dialkoxyamino group of formed N-methoxy-N-n-propyloxy-N’,N’-dimethylurea take place. |
URI: | http://repository.kpi.kharkov.ua/handle/KhPI-Press/36902 |
Appears in Collections: | Кафедра "Органічна хімія, біохімія, лакофарбові матеріали та покриття" |
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ECB_2014_3_9_Shtamburg_Methanolysis.pdf | 111,24 kB | Adobe PDF | ![]() View/Open |
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