Methanolysis of N-acetoxy-N-n-propyloxy-N’,N’-dimethylurea in different conditions
Дата
2014
ORCID
DOI
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Назва тому
Видавець
Deuton-X Ltd.
Анотація
The methanolysis of N-acetoxy-N-n-propyloxy-N’,N’-dimethylurea in the presence of strong acids at room temperatures or in the boiling methanol yields N,N-dimethoxy-N’,N’-dimethylurea as final product. Primarily the nucleophilic substitution acetoxy group at nitrogen on methoxy group arises. At second stage the transesterification of N,N-dialkoxyamino group of formed N-methoxy-N-n-propyloxy-N’,N’-dimethylurea take place.
Опис
Ключові слова
nucleophilic substitution, nitrogen, N-acyloxy-N-alkoxyureas, N,N-dialkoxyureas, methanolysis
Бібліографічний опис
Methanolysis of N-acetoxy-N-n-propyloxy-N’,N’-dimethylurea in different conditions / V. G. Shtamburg [et al.] // European Chemical Bulletin. – 2014. – Vol. 3, № 9. – P. 869-872.