Please use this identifier to cite or link to this item:
http://repository.kpi.kharkov.ua/handle/KhPI-Press/36903| Title: | Alcoholysis of N-acetoxy-N-alkoxycarbamates. Synthesis of NH-N,N-dialkoxyamines from N,N-dialkoxycarbamates |
| Authors: | Shtamburg, V. G. Anishchenko, A. A. Shtamburg, V. V. Tsygankov, A. V. Kostyanovsky, R. G. |
| Keywords: | nucleophilic substitution; nitrogen; N-acyloxy-N-alkoxycarbamates; alcoholysis; N,N-dialkoxycarbamates; hydrolysis |
| Issue Date: | 2014 |
| Publisher: | Deuton-X Ltd. |
| Citation: | Alcoholysis of N-acetoxy-N-alkoxycarbamates. Synthesis of NH-N,N-dialkoxyamines from N,N-dialkoxycarbamates / V. G. Shtamburg [et al.] // European Chemical Bulletin. – 2014. – Vol. 3, № 12. – P. 1119-1125. |
| Abstract: | The alcoholysis of N-acetoxy-N-alkoxycarbamates by methanol or ethanol at 20 – 40 °C yields N,N-dialkoxycarbamates and acetic acid. At the lower temperature the competitive formation of N,N’-bis(alkoxycarbonyl)-N,N’-bis(alkoxy)hydrazines can occur. The alkaline hydrolysis of N,N-dialkoxycarbamates yields NH-N,N-dialkoxyamines. |
| URI: | http://repository.kpi.kharkov.ua/handle/KhPI-Press/36903 |
| Appears in Collections: | Кафедра "Органічна хімія, біохімія, лакофарбові матеріали та покриття" |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| ECB_2014_3_12_Shtamburg_Alcoholisys.pdf | 190,39 kB | Adobe PDF |  View/Open |
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.