Please use this identifier to cite or link to this item: http://repository.kpi.kharkov.ua/handle/KhPI-Press/36903
Title: Alcoholysis of N-acetoxy-N-alkoxycarbamates. Synthesis of NH-N,N-dialkoxyamines from N,N-dialkoxycarbamates
Authors: Shtamburg, V. G.
Anishchenko, A. A.
Shtamburg, V. V.
Tsygankov, A. V.
Kostyanovsky, R. G.
Keywords: nucleophilic substitution; nitrogen; N-acyloxy-N-alkoxycarbamates; alcoholysis; N,N-dialkoxycarbamates; hydrolysis
Issue Date: 2014
Publisher: Deuton-X Ltd.
Citation: Alcoholysis of N-acetoxy-N-alkoxycarbamates. Synthesis of NH-N,N-dialkoxyamines from N,N-dialkoxycarbamates / V. G. Shtamburg [et al.] // European Chemical Bulletin. – 2014. – Vol. 3, № 12. – P. 1119-1125.
Abstract: The alcoholysis of N-acetoxy-N-alkoxycarbamates by methanol or ethanol at 20 – 40 °C yields N,N-dialkoxycarbamates and acetic acid. At the lower temperature the competitive formation of N,N’-bis(alkoxycarbonyl)-N,N’-bis(alkoxy)hydrazines can occur. The alkaline hydrolysis of N,N-dialkoxycarbamates yields NH-N,N-dialkoxyamines.
URI: http://repository.kpi.kharkov.ua/handle/KhPI-Press/36903
Appears in Collections:Кафедра "Органічна хімія, біохімія, лакофарбові матеріали та покриття"

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