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Title: Synthesis and structure of N-alkoxyhydrazines and N-alkoxy-N',N',N'-trialkylhydrazinium salts
Authors: Shtamburg, V. G.
Shishkin, O. V.
Zubatyuk, R. I.
Shtamburg, V. V.
Tsygankov, A. V.
Mazepa, A. V.
Kadorkina, G. K.
Kostyanovsky, R. G.
Issue Date: 2013
Publisher: Elsevier Inc.
Citation: Synthesis and structure of N-alkoxyhydrazines and N-alkoxy-N',N',N'-trialkylhydrazinium salts / V. G. Shtamburg [et al.] // Mendeleev Commun. – 2013. – Vol. 23, № 5. – P. 289-291.
Abstract: New types of 1,1,1-trialkyl-2-alkoxyhydrazinium chlorides and N-alkoxyhydrazines were obtained by reactions of N-chloro-N-alkoxyureas with trimethylamine or 1,4-diaza[2.2.2]bicyclooctane and by reactions of methyl N chloro-N-methoxycarbamate with potassium salt of N-acetylbenzenesulfonylamide. The XRD studies of N,N' bis(methoxycarbonyl)-N,N'-dimethoxyhydrazine, N'-methoxy-N'‑methoxycarbonyl-N-acetylbenzenesulfonylhydrazide and 1,1,1-trimethyl-2-methoxyhydrazinium perchlorate revealed the pyramidal configuration of the central nitrogen atoms in O–N–N geminal system, unusual elongation of N–N+ bond and shortening of N–OMe bond in 1,1,1-trimethyl-2-methoxyhydrazinium perchlorate.
Appears in Collections:Кафедра "Органічна хімія, біохімія, лакофарбові матеріали та покриття"

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