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Title: | Synthesis and structure of N-alkoxyhydrazines and N-alkoxy-N',N',N'-trialkylhydrazinium salts |
Authors: | Shtamburg, V. G. Shishkin, O. V. Zubatyuk, R. I. Shtamburg, V. V. Tsygankov, A. V. Mazepa, A. V. Kadorkina, G. K. Kostyanovsky, R. G. |
Issue Date: | 2013 |
Publisher: | Elsevier Inc. |
Citation: | Synthesis and structure of N-alkoxyhydrazines and N-alkoxy-N',N',N'-trialkylhydrazinium salts / V. G. Shtamburg [et al.] // Mendeleev Commun. – 2013. – Vol. 23, № 5. – P. 289-291. |
Abstract: | New types of 1,1,1-trialkyl-2-alkoxyhydrazinium chlorides and N-alkoxyhydrazines were obtained by reactions of N-chloro-N-alkoxyureas with trimethylamine or 1,4-diaza[2.2.2]bicyclooctane and by reactions of methyl N chloro-N-methoxycarbamate with potassium salt of N-acetylbenzenesulfonylamide. The XRD studies of N,N' bis(methoxycarbonyl)-N,N'-dimethoxyhydrazine, N'-methoxy-N'‑methoxycarbonyl-N-acetylbenzenesulfonylhydrazide and 1,1,1-trimethyl-2-methoxyhydrazinium perchlorate revealed the pyramidal configuration of the central nitrogen atoms in O–N–N geminal system, unusual elongation of N–N+ bond and shortening of N–OMe bond in 1,1,1-trimethyl-2-methoxyhydrazinium perchlorate. |
URI: | http://repository.kpi.kharkov.ua/handle/KhPI-Press/36984 |
Appears in Collections: | Кафедра "Органічна хімія, біохімія, лакофарбові матеріали та покриття" |
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