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Title: The properties and structure of N-chloro-N-methoxy-4-nitrobenzamide
Authors: Shtamburg, V. G.
Tsygankov, A. V.
Shishkin, O. V.
Zubatyuk, R. I.
Uspensky, B. V.
Shtamburg, V. V.
Mazepa, A. V.
Kostyanovsky, R. G.
Issue Date: 2012
Publisher: Elsevier Inc.
Citation: The properties and structure of N-chloro-N-methoxy-4-nitrobenzamide / V. G. Shtamburg [et al.] // Mendeleev Commun. – 2012. – Vol. 22, № 3. – P. 164-166.
Abstract: The XRD study of N-chloro-N-methoxy-4-nitrobenzamide revealed the high pyramidality degree of its amide nitrogen atom in O–N–Cl moiety. N-Chloro-N-methoxy-4-nitrobenzamide reacts with AcONa in MeCN selectively forming N-acetoxy-N-methoxy-4-nitrobenzamide, whereas its methanolysis in the presence of AcONa yields N,N' bis(4-nitrobenzoyl)-N,N'-dimethoxyhydrazine.
DOI: 10.1016/j.mencom.2012.05.019
Appears in Collections:Кафедра "Органічна хімія, біохімія, лакофарбові матеріали та покриття"

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