The properties and structure of N-chloro-N-methoxy-4-nitrobenzamide
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Elsevier Inc.
Abstract
The XRD study of N-chloro-N-methoxy-4-nitrobenzamide revealed the high pyramidality degree of its amide nitrogen atom in O–N–Cl moiety. N-Chloro-N-methoxy-4-nitrobenzamide reacts with AcONa in MeCN selectively forming N-acetoxy-N-methoxy-4-nitrobenzamide, whereas its methanolysis in the presence of AcONa yields N,N' bis(4-nitrobenzoyl)-N,N'-dimethoxyhydrazine.
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The properties and structure of N-chloro-N-methoxy-4-nitrobenzamide / V. G. Shtamburg [et al.] // Mendeleev Commun. – 2012. – Vol. 22, № 3. – P. 164-166.