Перегляд за Автор "Logvinkov, S. M."
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Документ Features of high-strength composite material structure creation(Kluwer Academic/Plenum Publishers, USA, 2015) Semchenko, G. D.; Makarenko, V. V.; Logvinkov, S. M.; Shuteeva, I. Yu.; Katyukha, A. S.The basis of technology proposed is use of a sol-gel method for preventing polycrystalline corundum fiber from crystallization during heating to high temperature and for low-temperature synthesis of prescribed phases in a corundum matrix with the aim of improving the operating properties of composite materials based on corundum. As a result of firing a charge based on corundum powder modified with tetraethoxysilane and polycrystalline corundum fiber modified with ethylsilicate-32 at 1360°C materials are created with very good strength properties. The materials exhibit electrical insulation properties and are stable in ionized gas streams at the level of known analogs as a result of creating self-reinforced mullite and β-SiC corundum matrix, reinforced with polycrystalline fiber and rapidly sintered due to presence of silicon oxynitride.Документ Modified alumina cement with high service properties(The editorial committee of China's refractories, 2016) Logvinkov, S. M.; Shabanova, G. N.; Korohodska, A. M.; Khrystych, E. V.This scientific paper gives consideration to the information on the contemporary structure of binary systems and three-component CaO – Al₂O₃ – ZrO₂ system required to select rational parameters for the synthesis of cementing agents. The production process of experimental clinker that has a Ca₇Al₆ZrO₁₈ composition has been described. The data of X-ray phase analysis and petrographic analysis of the experimental composition of special cement have been given and the reasons for availability of inappropriate phases have been analyzed. The processes of hydration hardening of the cement stone have been studied and the data of differential thermal analysis were used for the establishment of the hydration mechanism for basic crystal phases in the cement clinker composition. The differences in the hydration processes of experimental special cement were analyzed in comparison with known mechanisms. A possibility of the exploitation of special binder in contact with ZrO2 ( CaO–stabilized ) was tested using the specimens of fine concrete that were subjected to thermal treatment in different modes. The physical and mechanical properties of specimens and the mineralogical composition of concretes were given based on the data of X-ray analysis and the petrographic analysis. The cement additive was selected and its amount in the concrete composition was defined to slow-down the hardening and the mixture plasticization time. The relationships of physical and mechanical characteristics of concrete specimens were defined experimentally as a function of granulometric composition of the filler and thermal treatment temperature. The investigation data of corrosion resistance obtained using the static method were used to find out if experimental concretes can operate in contact with the steel-smelting alkaline slag.Документ Oxidation resistance of nano-reinforced PC-refractories modified with phenol formaldehyde resin. Part 4. Thermodynamic evaluation of phase formation within Mg–O–C–Al, Mg–O–C–Ni and МgO‒Al₂O₃‒NiO‒SiO₂ systems using SiC + Al + Ni (NiO) complex antioxidant(Kluwer Academic/Plenum Publishers, USA, 2017) Semchenko, G. D.; Borisenko, O. N.; Brazhnik, D. A.; Logvinkov, S. M.; Povshuk, V. V.; Shuteeva, I. Yu.; Angolenko, L. A.; Chopenko, N. S.; Vasyuk, P. A.Results are given for the synthesis and co-existence of phases formed from components of complex organic- inorganic antioxidant formed during modification of phenol-formaldehyde resin (PFR) and graphite with silica alkoxide and inorganic or organic nickel precursors. Thermodynamic analysis is given for the Mg–Al–C and Mg–O–Ni–C systems. It is shown that the periclase and carbon can coexist with aluminum and nickel, and also that oxidized antioxidants Al₂O₃ and NiO can interact respectively with the periclase and with the synthesized SiC formed during modification of PFR with silica. In considering the NiO‒MgO‒Al₂O₃‒SiO₂ system it is established that during service noble spinel will be synthesized from the complex antioxidant components, facilitating an increase in PC-refractory durability in service.