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  • Ескіз
    Документ
    Anodic dissolution of stainless steel in acid solutions
    (Таврійський національний університет ім. В. І. Вернадського, 2019) Shtefan, V. V.; Kanunnikova, Nadiia; Leshchenko, S. A.; Balamut, Nataliia
    In this work, the kinetics of anodic dissolution of stainless steel was studied using linear voltammetry. It is shown that an increase in the concentration of molybdates leads to an increase in anodic currents and an expansion in the region of active dissolution, which indicates that the oxoanions of the steel surface are passivated. The influence of electrolyte composition on the formation of a passive film was investigated. It has been established that at high potential sweep rates, dense layers of stoichiometric oxide do not have time to form and the passive film has a defective structure. Molybdenum-, zirconium-, aluminum-, titanium-containing compounds have been shown to increase the passivity area, which is the basis for the formation of protective oxide films on stainless steel.
  • Ескіз
    Документ
    Influence of chloride on the anode dissolution of aisi 304 steel
    (Sp. z o.o. "Diamond trading tour", 2018) Shtefan, V. V.; Kanunnikova, Nadiia; Balamut, Nataliia; Bofanova, Mariia
    The kinetics of anodic dissolution of stainless steel in acidic sulphate-chloride solutions was studied. The regularities of changes in the electrochemical parameters (stationary potential, passivation potential, passivation current density, transpassivation potential) with varying concentration of NaCl are established.