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Постійне посилання на розділhttps://repository.kpi.kharkov.ua/handle/KhPI-Press/35393
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Документ Sustainability Improvement of Kazakh Chemical Industry via Process Integration: A Case Study of Calcium Chloride Production(The Italian Association of Chemical Engineering, 2019) Boldyryev, Stanislav; Khussanov, Alisher; Gorbunov, Kostiantyn; Gorbunova, OlhaThis work presents the analysis of the calcium chloride concentration unit to reduce energy consumption and harmful emissions. The concentration of the calcium chloride in the raw materials is 14 % (mass) and a concentrated solution has 35 % of CaCl₂. Process Integration techniques were used for the analysis of the existing process to identify bottlenecks and disadvantages. A Pinch approach was executed to get real energy targets, energy gap and possible ways for process update. The authors proposed the solution for the process improvement using traced Grid Diagram and detailed simulation of the parameters of heat exchangers and evaporation units to get a feasible and economically beneficial retrofit. The representative case study of a Kazakh chemical factory was presented. There are some barriers to the development of the profitable and feasible solution, e.g. process constraints and limited performance of existing equipment. It forces developing a local methodology to apply the case study in an appropriate and most profitable way. The energy consumption of the inspected unit is 25 % higher than the target value. Nevertheless, the 1st feasible retrofit case with a detailed simulation of heat exchanger network parameters has only 17 % less energy consumption but, at the same time, the improved operating conditions of the evaporation unit were achieved. The 2nd retrofit option reduces the energy consumption by 22 % and more complicated network with additional operation changes was proposed. The results of this work may be used for the energy saving retrofit of the industrial evaporation units and decreasing the environmental impact of the chemical industry in Kazakhstan.Документ Possibility of Heat Pump use in Hot Water Supply Systems(2016) Babak, Tatyana; Duić, Neven; Khavin, G. L.; Boldyryev, Stanislav; Krajačić, GoranThe problem of modernization of the heat module with two-stage mixing scheme connection of hot water supply by installations of the heat pump during interheating period is considered. Heating water of the in-house circuit of the building heating system is used as a heat source for heat pump. The district cooling of the residential areas is possible through the heaters during the summer. R600 refrigerant is chosen for heat pump for its environmental-friendliness and low-pressure of evaporation and condensation. The economic calculation is made for interheating period comparing the operation with and without heat pump. This paper advances selection of optimum amount of heat to be recovered during low potential heat utilisation and targets for heating and cooling capacities.Документ Capital Cost Targeting of Total Site Heat Recovery(The Italian Association of Chemical Engineering, 2012) Nemet, Andreja; Boldyryev, Stanislav; Varbanov, Petar Sabev; Kapustenko, P. O.; Klemeš, Jiří JaromírExploiting heat recovery on Total Site level offers additional potential for energy saving through the central utility system. In the original Total Site Methodology (Klemeš et al., 1997) a single uniform ΔTmin specification was used. It is unrealistic to expect uniform ΔTmin for heat exchange for all site processes and also between processes and the utility system. The current work deals with the evaluation of the capital cost for the generation and use of site utilities (e.g. steam, hot water, cooling water), which enables the evaluation of the trade-off between heat recovery and capital cost targets for Total Sites, thus allowing to set optimal ΔTmin values for the various processes. The procedure involves the construction of Total Site Profiles and Site Utility Composite Curves and the further identification of the various utility generation and use regions at the profile-utility interfaces. This is followed by the identification of the relevant Enthalpy Intervals in the Balanced Composite Curves. A preliminary result for evaluation of heat recovery rate and capital cost can be obtained.