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  • Ескіз
    Документ
    Electrode processes in electrochromic anodic oxide films on niobium
    (Khalsa Publications, 2018) Gomozov, V. P.; Tulskiy, Gennadiy; Skatkov, L. I.; Deribo, S. G.; Tulskaya, Alena
    We review the following issues: peculiarities of polycrystalline AOP development at niobium in nitrate salt melt at temperatures of Nb₂O₅ recrystallization, the mechanisms of change in structure and properties of niobium pentoxide in the result of electrode processes under cathodic polarization (at the model structure of polycrystalline film), as well as the methods of amorphous electrochromic AOP development and ways of electrochromic processes optimization at such films.
  • Ескіз
    Документ
    Formation of nanostructures on the basis of porous anodic niobium oxide
    (Scientific and Technological Corporation "Institute for Single Crystals", 2019) Ryshchenko, I. M.; Lyashok, I. V.; Gomozov, V. P.; Vodolazhchenko, S. A.; Deribo, S. G.
    Self-organization of nanoscale structures under an electrochemical treatment is most pronounced during the formation of porous anodic metal (aluminum, titanium, niobium, and tantalum) oxides. A theoretical approach is proposed to describe the processes of the self-organization that allows one to determine the conditions for the formation of porous niobium oxides with amorphous or crystalline structure. The studies have shown the influence of the electrolyte nature on the formation of oxide layers. The use of an activator (fluoride) provides the conditions for the formation of oxides with different surface morphology at the initial stage of anodizing. By varying the mode of niobium anodizing, one can investigate the nature of pore nucleation at the initial stage of their growth, as well as track the in-time evolution of their geometrical dimensions, depending on the formation conditions, and synthesize porous AOFs on niobium with an amorphous or crystalline structure.