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Публікація Percolation effects in semiconductor IV-VI based solid solutions and thermoelectric materials science(Scrivener Publishing LLC, 2019) Rogacheva, E. I.; Nashchekina, O. N.The chapter reviews the present status of our experimental studies aimed at con firming the existence of anomalies in the dependences of thermoelectric (TE) and other properties on composition in semiconductor IV-VI–based solid solutions in the region of small impurity concentration. For all studied solid solutions, we observed an anomalous behavior of the isotherms of electrical conductivity, phonon thermal conductivity, heat capacity, charge carrier mobility, microhardness, the Seebeck coefficient, and TE figure of merit in the vicinity of (0.5–1) at. % of impurity. We believe that the observed phenomenon is connected with the existence of percolation-type phase transitions corresponding to the transition from dilute solid solutions to the impurity continuum and is accompanied by self-organization processes. The non-monotonic behavior of the concentration dependences of the TE properties and the underlying percolation phenomena should be taken into consideration when developing efficient TE materials and optimizing their properties. To get additional confirmation of the assumption regarding the universal character of phase transitions connected with the formation of the impurity continuum, it is necessary to expand the range of objects to be studied as well as spectrum of properties to be measured.Публікація Percolation effects and self-organization processes in cold-pressed Bi2(Te1−xSex)3 solid solutions(Elsevier Ltd, 2021) Rogacheva, E. I.; Martynova, E. V.; Shelest, T. N.; Doroshenko, A. N.; Nashchekina, O. N.It was established that the dependences of thermoelectric and mechanical properties of cold-pressed Bi2(Te1−xSex)3 alloys on composition (x = 0–0.07) exhibit a non-monotonic behavior in certain concentration ranges: an anomalous decrease in the Seebeck coefficient, thermoelectric power factor, and microhardness, and increase in electrical conductivity with increasing x. We observed similar anomalies earlier for cast Bi2(Te1−xSex)3 alloys and explained them by percolation and self-organization phenomena. Thus, the existence of the anomalies does not depend on the method of sample preparation. However, in pressed samples as compared to cast ones conductivity type changes from p to n and thermoelectric power factor increases.Документ Quantum size effects and thermoelectric properties of IV-VI-based 2D-nanostructures(Національна академія наук України, 2019) Rogacheva, E. I.Публікація Temperature and magnetic field dependences of thermoelectric properties of Bi1-xSbx solid solutions in the range x = 0 – 0.25(Easy Conferences Ltd, 2019) Rogacheva, E. I.; Doroshenko, A. N.; Nashchekina, O. N.Документ Effect of cold pressing on the concentration dependences of thermoelectric properties of (Bi1-xSbx)2Te3 solid solutions (x = 0 – 0.07)(FOP Mezina, 2018) Martynova, K. V.; Rogacheva, E. I.Документ Deviation from Stoichiometry and Temperature Dependences of Thermoelectric Properties of Bi2Te3 Crystals and Thin Films(Прикарпатський національний університет імені Василя Стефаника, 2019) Rogacheva, E. I.; Novak, K. V.; Budnik, A. V.; Men'shov, Yu. V.Публікація Influence of Composition on the Thermoelectric Properties of Bi1-xSbx Thin Films(IOP Publishing Ltd, 2016) Rogacheva, E. I.; Nashchekina, O. N.; Doroshenko, A. N.; Sipatov, A. Yu.; Dresselhaus, M. S.Документ Thermoelectric properties of polycrystalline Bi₁₋ₓSbₓ solid solutions in the concentration range x = 0 – 0.25(National Academy of Sciences of Ukraine, 2016) Doroshenko, A. N.; Rogacheva, E. I.; Drozdova, A. A.; Martynova, K. V.; Men'shov, Yu. V.A detailed investigation of the dependence of thermoelectric properties of polycrystalline Bi₁₋ₓSbₓ solid solutions on composition in a wide concentration range (x = 0 – 0.25) was performed at room temperature. The objects of study were cast samples of various composition obtained by ampoule method in one technological cycle consisting in cooling of ampoules with melts in the air and subsequent long homogenizing annealing at temperature (520 ± 5) K for 720 hours. It was shown that the composition dependences of properties are of clearly expressed nonmonotonic type. The presence of concentration anomalies of thermoelectric properties was confirmed that had been earlier observed in the range x = 0 – 0.1 on cast samples after different kinds of thermal treatment and interpreted as manifestation of electron phase transitions. A complicated nature of dependences at x > 0.1 is attributable to qualitative changes in Bi₁₋ₓSbₓ band structure at certain critical compositions, a change in relative contribution to conductivity of charge carriers from different energy bands with a change in antimony concentration and high sensitivity of energy spectrum and physical properties of Bi₁₋ₓSbₓ к to external effects.Документ Thermoelectric and mechanical properties of (Bi₁₋ₓSbₓ )₂Te₃(x = 0÷0.07) semiconductor solid solutions(National Academy of Sciences of Ukraine, 2016) Rogacheva, E. I.; Martynova, K. V.; Bondarenko, A. S.The dependences of thermoelectric properties and microhardness on the composition of polycrystalline (Bi₁₋ₓSbₓ )₂Te₃ solid solutions in the concentration range x = 0÷0.07 at room temperature were investigated. A drastic growth of microhardness was discovered with a simultaneous reduction of the Hall coefficient, the Seebeck coefficient and electric conductivity with increase in antimony content x = 0.005 – 0.01, following which with further increase in x to x = 0.01 – 0.015, the type of the dependences was reversed. The observed effect is attributable to a high degree of crystal lattice disorder with the introduction of the first portions of impurity and to subsequent relaxation processes with formation of percolation channels in crystal impurity subsystem. With further increase in x, the Hall coefficient and the Seebeck coefficient practically do not change with composition, and the observed more complicated dependence of microhardness and electric conductivity on x is interpreted as a manifestation of short-range processes in a solid solution.Документ Size effects in thin n-PbTe films(STC "Institute for Single Crystals", 2015) Menshikova, S. I.; Rogacheva, E. I.; Sipatov, A. Yu.; Zubarev, Evgeniy N.