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  • Ескіз
    Документ
    Development of technology for forming vacuum-arc TiN coatings using additional impulse action
    (Institute for Single Crystals, 2022) Pinchuk, N. V.; Starikov, V. V.; Kniazieva, H. O.; Surovytskyi, S. V.; Konotopska, N. V.
    The effect of supplying a constant and high-voltage pulse with duration of 10 μs on the formation of predominantly oriented crystallites and the stress-strain state of vacuum-arc TiN coatings at two pressures of a nitrogen atmosphere is analyzed. It is shown that the deposition of the coatings under conditions of high voltage cascading effect leads to the growth of crystallites with the texture axis [110]. and to a change in the stress-strain state (reduction of deformation in the group of crystallites with the axis [111]). The obtained results are explained by an increase in the mobility of atoms and ordering processes in the region of the displacement cascades formed under the action of bombarding high-energy ions accelerated in the field of high-wave pulse potential. Computer simulations of the main processes observed during deposition were performed.
  • Ескіз
    Документ
    Stimulation of calcium phosphate crystal formation by implant surfaces with electret properties
    (Collegium Basilea & AMSI, 2015) Starikov, V. V.; Starikova, S. L.; Mamalis, A. G.; Lavrynenko, S. N.
    Oxide coatings with electret properties are investigated. The possibility of stimulation of the formation of calcium phosphate sediments near the electroactive surface is discussed. The exposure of implants with such coatings to solutions imitating blood plasma showed their high efficiency of biointegration due to activation of an exchange processes in living tissues by a negative superficial charge. The revealed effect amplifies with the growth of the thickness of the anodic oxide film.
  • Ескіз
    Документ
    Features of medical implant passivation using anodic oxide films
    (Collegium Basilea & AMSI, 2016) Starikov, V. V.; Starikova, S. L.; Mamalis, A. G.; Lavrynenko, S. N.
    The passivation ability of metals from groups IV and V of the Periodic Table is considered. Anodic treatment is able to neutralize the increase of metal hardening when comminuting grains to nanometre sizes. The deposition of metal oxide film coatings on a cobalt–chromium alloy surface results in substantial passivation of its surface and prevents cobalt and chromium accumulation in bone tissues. The decrease of surface activity of titanium implants can be achieved both by cleaning the surface during vacuum annealing before oxidation and by the increase of the anodic oxide film thickness, which limits mass and charge transfer through the implant surface. Recommended titanium implant treatment regimens are vacuum annealing at 650 °C and anodic oxidation to attain an oxide thickness less or equal to 300 nm.