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  • Ескіз
    Документ
    Investigation of diamond biocompatible coatings for medical implants
    (Харківський національний університет ім. В. Н. Каразіна, 2015) Starikov, V. V.; Starikova, S. L.
    Despite the advantages of diamond-like carbon fi lms that are used as wear-resistant coatings for implants, they may have a number of disadvantages such as the high level of internal tension, low adhesive durability and high sensitivity to environment conditions. These problems can be overcome by application of the new carbon nanocomposite coatings that can be deposited from C60 ionic beam. It was found that the proposed diamond-like nanocomposite coatings increase implant material resistance to electrochemical corrosion processes due to shift of its electrode potential to area of positive values, and also promote a complex of reparative and adaptation and compensatory reorganizations that will allow to accelerate processes of healing and postoperative adaptation of organism in zone of implant inputting.
  • Ескіз
    Документ
    Stimulation of calcium phosphate crystal formation by implant surfaces with electret properties
    (Collegium Basilea & AMSI, 2015) Starikov, V. V.; Starikova, S. L.; Mamalis, A. G.; Lavrynenko, S. N.
    Oxide coatings with electret properties are investigated. The possibility of stimulation of the formation of calcium phosphate sediments near the electroactive surface is discussed. The exposure of implants with such coatings to solutions imitating blood plasma showed their high efficiency of biointegration due to activation of an exchange processes in living tissues by a negative superficial charge. The revealed effect amplifies with the growth of the thickness of the anodic oxide film.
  • Ескіз
    Документ
    Properties of magnetron hydroxyapatite coatings deposited on oxidized substrates
    (Collegium Basilea & AMSI, 2016) Starikov, V. V.; Kostuchenko, A. V.; Starikova, S. L.; Mamalis, A. G.; Lavrynenko, S. N.
    Hydroxyapatite (HA) coating were formed on oxidized niobium surfaces by the highfrequency magnetron sputtering method using hydroxyapatite and tricalcium phosphate targets. The structure, substructure and mechanical properties of the Nb–Nb2O5–HA system were investigated by X-ray diffraction, atomic force microscopy and nanoindentation and the stress state was assessed. The synthesized hydroxyapatite film had the following characteristics: thermal expansion coefficient 10–5 K–1; modulus of elasticity 120 GPa; adhesive strength not less than 0.45 kg/mm2; density 2900 kg/m3. The stress magnitude in the metal oxide substrate was from 11 to 14 MPa after hydroxyapatite film deposition.
  • Ескіз
    Документ
    Features of medical implant passivation using anodic oxide films
    (Collegium Basilea & AMSI, 2016) Starikov, V. V.; Starikova, S. L.; Mamalis, A. G.; Lavrynenko, S. N.
    The passivation ability of metals from groups IV and V of the Periodic Table is considered. Anodic treatment is able to neutralize the increase of metal hardening when comminuting grains to nanometre sizes. The deposition of metal oxide film coatings on a cobalt–chromium alloy surface results in substantial passivation of its surface and prevents cobalt and chromium accumulation in bone tissues. The decrease of surface activity of titanium implants can be achieved both by cleaning the surface during vacuum annealing before oxidation and by the increase of the anodic oxide film thickness, which limits mass and charge transfer through the implant surface. Recommended titanium implant treatment regimens are vacuum annealing at 650 °C and anodic oxidation to attain an oxide thickness less or equal to 300 nm.
  • Ескіз
    Документ
    Diamond biocompatible coatings for medical implants
    (Collegium Basilea & AMSI, 2016) Starikov, V. V.; Starikova, S. L.; Mamalis, A. G.; Lavrynenko, S. N.
    New carbon (diamond-like) nanocomposite coatings deposited from a C60 ionic beam can be used as a wear-resistant protective coating for implants. It was found that these coatings enhance resistance to тelectrochemical corrosion processes due to a shift of the material’s electrode potential to a zone of positive values. They also promote a complex of reparative, adaptative and compensatory reorganization that accelerates the healing processes in the vicinity of the implant.