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Документ Determination of kinetic characteristics of heat and mass exchange in a column heat exchanger with direct phase contact(РС Tесhnology сеntеr, 2024) Tseitlin, Musii; Shkop, Andrii; Shestopalov, Oleksіi; Raiko, Valentina; Ponomarova, NataliiaОб’єктом дослідження були процеси тепломасообміну в колонному теплообміннику з безпосереднім контактом фаз. Досліджувана проблема пов’язана з необхідністю визначення оцінок кінетичних характеристик теплообміну при концентруванні розчинів у контактному теплообміннику, оснащеному двопоточними тарілками. Зокрема, передбачалося, що визначення впливу швидкості газу в апаратові і щільності зрошення тарілок рідиною, а також геометрії тарілок, на кінетичні коефіцієнти дасть змогу виявити закономірності теплообміну і масообміну між рідиною і контактуючим з нею повітрям в колонному апарату. Визначено, що для збільшення інтенсивності масообміну в газі та теплообміну в рідині необхідно збільшувати значення швидкості газу та щільності зрошення. Тоді швидкість газу та щільність зрошення приблизно однаково впливають на інтенсивність масообміну в газі та теплообміну в рідині. При дослідженні впливу геометрії тарілки на кінетичні коефіцієнти тепловіддачі в рідині та масообміну в газі встановлено, що величина частки вільного перерізу тарілки має вирішальний вплив на значення розглянутих кінетичних коефіцієнтів. Отримано узагальнене рівняння, яке дає змогу не тільки розрахувати коефіцієнт передачі ентальпії при взаємодії розчину хлориду натрію з повітрям, а й визначити лімітуючу стадію цього процесу. Отримані результати можуть бути використані в розробці установки концентрування гарячого розчину хлориду натрію випаровуванням води при продуванні повітрям в контактному теплообміннику. Це може дати змогу отримання кристалічного хлориду натрію з використанням вторинних енергоресурсів та інших нетрадиційних джерел теплової енергії.Документ Studying patterns in the flocculation of sludges from wet gas treatment in metallurgical production(PC Technology center, 2019) Shestopalov, Oleksii; Briankin, Oleksandr; Tseitlin, Musii; Raiko, Valentina; Hetta, Oksana S.The influence of a solid phase concentration in the model sludges of wet gas purification, as well as the flocculant consumption, on a change in the solid phase sedimentation rate and the strength of floccules has been examined. This is important because fluctuations in the solid phase concentration in waste water represent an uncontrolled process that significantly affects the kinetics of the solid phase sedimentation and leads to an increase in the flocculant consumption. We have proposed a procedure for determining the sedimentation rate of the flocculated sludge and the strength of floccules following the hydromechanical influence, which takes into consideration the solid phase concentration and the flocculant consumption. The study was carried out on model waste water, synthesized by mixing the dust from dry gas purification at actual production site with water. It has been determined that the solid phase concentration affects the rate of floccule deposition. It has been established that the optimum conditions for aggregate formation within a given model system are observed at the solid phase concentration in the interval 8–12 g/l. Increasing the solid phase concentration above 16 g/l decreases the floccule sedimentation rate disproportionately to the flocculant concentration. It is possible to reduce flocculant consumption and to optimize its dosage by carrying out a cleaning process taking into consideration the specified patterns. It was established that the hydromechanical influence on aggregates exerts the destructive effect, whose degree depends on the solid phase concentration. In particular, increasing the rate of fluid motion leads to greater damage to floccules than increasing the time for a less intense exposure. The way to minimize the destructive effect on floccules could be lowering the suspension transportation speed resulting from a decrease in the installation performance or through the increased cross-section of the channel (a pipeline). An increase in the solid phase concentration of the model system above 16 g/l is accompanied by a significant reduction in the strength of floccules. Therefore, when designing wastewater treatment plants that utilize flocculants, it is necessary to provide optimum conditions for aggregation and to minimize the hydromechanical effects on floccules by lowering the velocity of fluid motion.Документ Ratio between heat and mass transfer when concentrating the solution in a cooling tower(Lviv Polytechnic National University, 2019) Tseitlin, Musii; Raiko, ValentinaThe ratio between the intensity of the mass transfer in gas and the heat transfer in liquid during the evaporative solution concentration has been studied. It was determined that the share of liquid resistance in the total resistance to enthalpy transfer increases in the temperature range from 30 to 50°C by almost 2 times, and reaches 40 %. The technique has been developed for the separate determination of the mass transfer coefficients in gas and heat transfer in liquid.Документ Analysis of ways reducing drilling waste in oil and gas production influencing on natural environment(UNIVERSITAS Publishing, Romania, 2019) Shestopalov, Oleksii; Rykusova, N. I.; Tseitlin, Musii; Raiko, ValentinaДокумент A study of the flocculs strength of polydisperse coal suspensions to mechanical influences(Scientific Route, 2017) Shkop, Andrii; Tseitlin, Musii; Shestopalov, Oleksii; Raiko, ValentinaThe effect of the concentration and disperse composition on the flocculation strength to mechanical influence is investigated. It is found that the residual rate of floccules sedimentation after the mechanical influence at a constant rate of flocculant has a maximum value at a concentration of solids in the slime in the range of 7–30 g/dm3. The best results are obtained in all the experiments at a solids concentration of 10 g/l. It is found that at a concentration up to 7 g/l and more than 30 g/l, the floccules is formed. They have the lowest residual rate after mechanical influences. With increasing content of the solid fraction of 40–100 microns over 15 %, the strength of floccules increases. They retain their shape and relatively high sedimentation rate even after mechanical influence. The obtained data allow to recommend correction of the slime composition before flocculant injection both the concentration close to the optimum, and the content of size fraction of 40–100 mm more than 15 %.Документ A study of wastewater treatment conditions for the poultry meat processing enterprise(Технологічний центр, 2018) Makhlay, Konstantyn; Tseitlin, Musii; Raiko, ValentinaFor the local treatment of wastewater of food industry enterprises, physicochemical treatment methods are widely used, which, with properly selected reagents and their doses, allow achieving high treatment efficiency. At the same time, doses of reagents and conditions for their use can differ sharply between enterprises, therefore the regularities of the treatment process must be studied at a particular drain. In the paper, the regularities of the process of wastewater coagulation by coagulants and flocculants of different chemical composition are examined on the example of the wastewater of the turkey meat processing enterprise. The regularities of the process of wastewater coagulation in a wide range of pH values of the medium are studied. It is experimentally determined that the optimum pH of the medium for the use of polyaluminum chloride is in the range 5.9÷6.4, iron chloride 6.2÷6.7, iron sulfate 5.1÷5.7. The regularities of the effect of the coagulant dose on the efficiency of suspended solids removal from wastewater and color reduction are established. Based on the data obtained, the most optimum doses of coagulants are determined. The rational dose of polyaluminum chloride was 140 mg/l, iron sulfate – 110 mg/l and iron chloride – 80 mg/l. The regularities of the process of wastewater flocculation with the use of flocculants of different charges and molecular weight are investigated. The most effective types of flocculants are determined, and optimum reagent doses are established. The rational conditions for physicochemical wastewater treatment using coagulants and flocculants are determined. The obtained data make it possible to optimize the operation of local treatment facilities of the poultry processing enterprise: to increase performance, as well as to reduce operating costs. The selected binary combinations of reagents allow achieving the efficiency of suspended solids removal of 99.4 % and color reduction – 82.4 %.Документ Study of the strength of flocculated structures of polydispersed coal suspensions(Технологічний центр, 2017) Shkop, Andrii; Tseitlin, Musii; Shestopalov, Oleksii; Raiko, ValentinaThe influence of concentration, dispersed composition and degree of thickening of the flocculated slime on the strength of floccules was studied. It was revealed that for the formation of durable aggregates of polydispersed coal slime it is recommended to apply the combination of the non-ionogenic and anionogenic flocculant in the ratio of 20:80 % respectively. It was established that the residual sedimentation rate of floccules after mechanical influence at the constant consumption of the flocculant has the greatest value at the concentration of solid phase in slime of 10–30 g/dm3. With an increase in the content of the portion of solid phase with coarseness of more than 40 µm, the strength of floccules increases to the larger degree than the influence of the initial concentration. This makes it possible to recommend the correction of the slime composition not only by the concentration, but also by the content of medium grade of more than 15–20 %. It was shown that with an increase in the degree of thickening of more than 140–150 g/l the resistance of aggregates to mechanical influence substantially decreases due to an increase in pseudo-plastic properties of flocculated slime.