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  • Ескіз
    Документ
    Internal stresses and magnetic properties of Fe-Co electrolytic coatings
    (Науково-технологічний комплекс "Інститут монокристалів", 2017) Proskurina, V. O.; Yermolenko, I. Yu.; Zyubanova, S. I.; Shipkova, I. G.; Avramenko, B. A.; Sachanova, Yu. I.
    Consideration was given to the effect of electrolysis parameters on the composition and the properties of electrolytic iron-cobalt film coatings obtained from citrate electrolytes. The interconnection between the film composition and the film thickness with its internal stresses and magnetic properties has been studied. It was established that Fe60Co40 alloys show the lowest level of internal stresses for the saturation induction of 1.8 to 2.1 Tl.
  • Ескіз
    Документ
    Surface analysis of Fe-Co-Mo electrolytic coatings
    (IOP Publishing Ltd, 2017) Yar-Mukhamedova, G. Sh.; Sakhnenko, N. D.; Ved, M. V.; Yermolenko, I. Yu.; Zyubanova, S. I.
    Coatings Fe-Co-Mo with a composition of 47 at.% iron, 28 at.% Cobalt and 25 at.% Molybdenum were deposited from citrate electrolyte using pulse electrolysis mode. Scanning electron and atomic force microscopy have established the surface morphology and topography. It was identified the parts with a globular structure which have an average size of 0.2-0.5μm and singly located sharp grains. Within the same scan area sites with developed surface were detected the topography of which is identical to the crystal structure of cobalt with the crystallites size of 0.2–1.75μm. The parameters Ra and Rq for parts with different morphology as well as average characteristics of coatings demonstrated the low roughness of the surface. It is found that the coercive force of Fe-Co-Mo films is 7-10 Oe, which allow us to classify the Fe-Co-Mo coatings as soft magnetic materials.
  • Ескіз
    Документ
    Electroplating and functional properties of amorphous Fe-Mo(W) and Fe-Mo-W coatings
    (Институт химии растворов им. Г. А. Крестова РАН, 2015) Karakurkchi, A. V.; Ved, M. V.; Sakhnenko, N. D.; Yermolenko, I. Yu.; Zyubanova, S. I.
  • Ескіз
    Документ
    Functional properties of multicomponent galvanic alloys of iron with molybdenum and tungsten
    (Institute for Single Crystals, 2015) Karakurkchi, A. V.; Ved, M. V.; Sakhnenko, N. D.; Yermolenko, I. Yu.; Zyubanova, S. I.; Kolupayeva, Z. I.
    Galvanic alloy coatings Fe-Mo (W) and Fe-Mo-W were deposited from citrate bath based on Fe (III) using both direct and pulsed current on substrates steel 3 and grey cast iron GC 18. It was shown that the alloying components content, their distribution on the surface, morphology and topography of the coatings are depended on the electrolysis mode. It was established that the functional properties of the binary and ternary alloys of iron (corrosion resistance, microhardness, antifriction et al.) exceed parameters of the substrate and are predetermined by the composition, structure, material and surface roughness.
  • Ескіз
    Документ
    Electrodeposition of iron-molybdenum coatings from citrate electrolyte
    (Pleiades Publishing, 2014) Ved, M. V.; Sakhnenko, N. D.; Karakurkchi, A. V.; Zyubanova, S. I.
    Specifi c features of the electrodeposition of iron–molybdenum coatings from a citrate electrolyte based on iron(III) sulfate and sodium molybdate in dc and unipolar pulsed modes were studied. It was demonstrated that bright compact coatings with varied content of molybdenum can be produced by varying the relative concentrations of salts of the alloy-forming components and the solution pH. The current density ranges providing the high efficiency of the galvanostastic electrolysis were determined and it was shown that using the pulsed mode makes smaller the amount of nonmetallic impurities in a coating, diminishes its roughness and leads to formation of surface layers with a more uniform composition, The iron–molybdenum coatings exhibit a high corrosion resistance in corrosive media and physicomechanical properties improved as compared with the base metal, which makes it possible to recommend these coatings for protection from corrosive-mechanical disintegration and restoration of the surface of worn articles.