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Постійне посилання на розділhttps://repository.kpi.kharkov.ua/handle/KhPI-Press/35393
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Документ Structure and Properties of Vacuum-arc Coatings of Chromium and Its Nitrides Obtained under the Action of Constant and Pulse High-voltage Bias Potential(Sumy State University, 2017) Sobol, O. V.; Postelnyk, A. A.; Mygushchenko, R. P.; Al-Qawabeha, Ubeidulla F.; Tabaza, Taha A.; Al-Qawabah, Safwan M.; Gorban, V. F.; Stolbovoy, V. A.To reveal the regularities of structural engineering of vacuum-arc coatings based on chromium and its nitrides, the influence of the main physicotechnological factors (the pressure of the nitrogen atmosphere and the bias potential) in the formation of coatings was studied. It was discovered that during the deposition of chromium coatings the formation of the texture axis [100], as well as the macrodeformation of compression is happening. The supply of a high-voltage negative pulse potential to the substrate increases the mobility of the deposited atoms and leads to relaxation of the compression deformation. As the pressure increases from Torr, the phase composition of the coatings changes: Cr (JCPDS 06-0694) → Cr2N(JCPDS 35-0803) → CrN(JCPDS 11-0065). The supply of high-voltage pulses leads to the formation of a texture of crystallites with parallel growth surfaces planes having d ≈ 0.14 nm. The structure obtained by pulsed high-voltage action makes it possible to increase the hardness of the coating to 32 GPa and reduce the friction coefficient to 0.32 in the "chromium nitride-steel" system and to 0.11 in the "chromium nitride-diamond" system. The results obtained are explained from the viewpoint of increasing the mobility of atoms and the formation of cascades of displacements when using an additional high-voltage potential in the pulse form during the deposition of chromium-based coatings.Документ The Effect of Constant and High Voltage Pulse Bias Potentials on the Structure and Properties of Vacuum-Arc (TiVZrNbHf)Nₓ Coatings(Sumy State University, 2018) Sobol, O. V.; Postelnyk, A. A.; Mygushchenko, R. P.; Gorban, V. F.; Stolbovoy, V. A.; Zvyagolskiy, A. V.The effect of constant (Ub) and high voltage pulse (Uip) bias potentials supplied to the substrate during condensation, on the structure and properties of vacuum-arc (TiVZrN-Hf)Nх coatings has been studied. It has been determined that the number and size of the drop phase decreases with increasing Ub. The use of Uip promotes a more uniform growth in the coating volume. It is shown that due to the increase of Ub from 0 to 200 V in nitride coatings of high entropy alloys, it is possible to change the growth texture [100] to [111]. This results in increased hardness from 32 GPa to 49 GPa. The supply of high voltage potential in a pulse form leads to a relative decrease in the average size of crystallites and the formation of a bi-texture state. Conditions and mechanisms of the preferential crystallites orientation (axial texture) of vacuum arc (TiVZrNbHf)Nх coatings and texture influence on mechanical properties have been discussed.Документ The use of plasma-based deposition with ion implantation technology to produce superhard molybdenum-based coatings in a mixed (C2H2+N2) atmosphere(2018) Sobol, O. V.; Andreev, A. A.; Mygushchenko, R. P.; Beresnev, V. M.; Meylekhov, A. A.; Postelnyk, A. A.; Kravchenko, S. A.; Tabaza, Taha. A.; Al-Qawabah, Safwan M.; Al-Qawabeha, Ubeidulla F.; Stolbovoy, V. A.; Serdyuk, I. V.; Kolesnikov, D. A.; Kovaleva, M. G.The influence of the pressure of a mixed gaseous atmosphere (80%C2H2+20%N2) and the supply of a high-voltage negative potential in a pulsed form on the elemental and phase composition, structure and physico-mechanical characteristics of the vacuum-arc molybdenum-based coatings. It is shown that in the temperature deposition range 400…550 °С as a result of plasma-chemical reactions, the maximum nitrogen atoms content in the coating does not exceed 1.5 at.%. It is found, that at the maximum pressure of РC2H2+N2= 2.3∙10-1 Pа when the γ-MoC phase is formed, an superhard state of 50.5 GPa (at a constant potential -200 V, without additional high-voltage pulse action) and 51.1 GPa (at a constant potential -200 V, with additional high-voltage pulse action) is reached.Документ Influence of pressure of working atmosphere on the formation of phase-structural state and physical and mechanical properties of vacuum-arc multilayer coatings ZrN/CrN(2016) Sobol, O. V.; Andreev, A. A.; Gorban, V. F.; Stolbovoy, V. A.; Meylekhov, A. A.; Postelnyk, A. A.; Dolomanov, A. V.For multilayer coating system ZrN/CrN determined the effect of the pressure of the working atmosphere of nitrogen (Pɴ), DC (˗Us) and pulse (-Ui) negative bias potential during the deposition and the thickness of the layers in the period on the phase composition, texture, substructural characteristics and physical-mechanical properties. It is found that for Рɴ = (2.2...12)·10-4 Torr in the layers of chromium nitride formed on a lower nitrogen phase with the β-Cr2N simple hexagonal crystal lattice, and in the zirconium nitride layers are formed of a stoichiometric ZrN phase with a cubic lattice. Such a multilayer coating (layer thickness about 50 nm) at the maximum in this range Pɴ = 1.2·10-3 Torr is most solid (39 GPa) with a modulus of elasticity of 268 GPa and the ratio H/E = 0.145. At higher Pɴ, when the layers are formed phase stoichiometric composition with homogeneous crystal lattices (ZrN and СrN) hardness of the composition is not more than 33 GPa. The mechanisms of the effects observed are based on the higher barrier properties of the interphase boundary layers with different types of crystal lattices was discussed.