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  • Ескіз
    Публікація
    Concentration dependences of galvanomagnetic and thermoelectric properties of Bi1-xSbx thin films in the range x = 0 – 0.25
    (Національна академія наук України, 2019) Rogacheva, E. I.; Doroshenko, A. N.; Sipatov, A. Yu.; Nashchekina, O. N.
  • Ескіз
    Публікація
    Percolation effects and self-organization processes in Bi₂(Te₁₋ₓSeₓ)₃ solid solutions
    (Easy Conferences Ltd, 2019) Rogacheva, E. I.; Shelest, T. N.; Martynova, E. V.; Doroshenko, A. N.; Nashchekina, O. N.
  • Ескіз
    Публікація
    Temperature and magnetic field dependences of thermoelectric properties of Bi1-xSbx solid solutions in the range x = 0 – 0.25
    (Easy Conferences Ltd, 2019) Rogacheva, E. I.; Doroshenko, A. N.; Nashchekina, O. N.
  • Ескіз
    Публікація
    Electronic phase transitions in thin films of Bi1-xSbx solid solutions
    (Grupo Pacifico, 2018) Rogacheva, E. I.; Doroshenko, A. N.; Nashchekina, O. N.
  • Ескіз
    Публікація
    Percolation effects and self-organization processes in Bi₂(Te₁₋ₓSeₓ)₃ solid solutions
    (Науково-технологічний комплекс "Інститут монокристалів", 2019) Rogacheva, E. I.; Shelest, T. N.; Martynova, E. V.; Doroshenko, A. N.; Nashchekina, O. N.; Men'shov, Yu. V.
    The room-temperature dependences of microhardness H, electrical conductivity σ, the Seebeck coefficient S, and thermoelectric power factor P on composition of Bi₂(Te₁₋ₓSeₓ)₃ solid solutions were measured in the concentration range x = 0 - 0.07. In the intervals x = 0.0075 - 0.0175 and x = 0.025 - 0.035, an anomalous decrease in H and S and increase in σ with increasing x were observed. The first concentration-dependent anomaly was attributed to critical phenomena, accompanying a percolation-type phase transition. The percolation threshold xc and the radius of deformation spheres R₀ around Se impurity atoms were estimated. The second anomaly is assumed to be connected with a short-range ordering in the solid solution. The non-monotonic character of the dependences of H on the load on an indenter, whose behavior depended on the impurity concentration, was attributed to the interaction of the deformation fields created by dislocations and impurity atoms.
  • Ескіз
    Публікація
    Temperature and concentration dependences of specific heat of Bi₁₋ₓSbₓ solid solutions
    (Науково-технологічний комплекс "Інститут монокристалів", 2018) Rogacheva, E. I.; Doroshenko, A. N.; Nashchekina, O. N.
    For Bi₁₋ₓSbₓ solid solutions, the concentration (x = 0 - 0.12) and temperature (170-525 K) dependences of specific heat Cp were obtained. At all temperatures studied, three peaks of Cp were observed near x = 0.015, x = 0.037, and x = 0.07. The observed effects were attributed to critical phenomena accompanying the second-order phase transitions: percolation transition from dilute to concentrated solid solutions, the transition to a gapless state, and the semimetal-semiconductor transition, respectively. It was shown that the values of critical indexes (α = 0.11 ± 0.01) are the same not only for different peaks but also for different temperatures and correspond to the values theoretically calculated within the framework of scale-invariant theory for three-dimensional (3D) models.