Исследование изменения физико-химических свойств водопроводной воды под воздействием мощных подводных искровых разрядов

Abstract

Представлены результаты экспериментального исследования изменения физико-химических свойств водопроводной воды под воздействием мощных подводных искровых разрядов атмосферного давления. Выявлена зависимость изменения окислительно-восстановительного потенциала и рН обрабатываемой воды от параметров импульсов, задаваемых параметрами электрической разрядной цепи, и их количеством. Исследования проведены на разрядных электродах, изготовленных из материалов двух типов: нержавеющая сталь и графит.

Purpose. The purpose of this investigation is to study the changes in the redox potential and pH-value of the tap water as a function of underwater spark discharges, storage device capacitance and the charging voltage. Methodology. To define the electric parameters of discharge circuit we used the Rogowski loop and the сompensated capacitance-ohm potential divider. To determine water properties before and after the treatment we used the following devices: the water analyzer Anion-7051 with the limit of absolute error of the EMF measurement ± 2 mV, the BANTE 902 device with the absolute error of ± 0.002 рН. Results. We managed to establish the time of the origination of changes in the properties of treated water. A change in the positive redox potential to a negative one occurred already after the third pulse at a total energy input of ≥ 1 kJ. The pH value increased in the range of 0.2-0.45 рН units. We obtained the relationship of a change in the redox potential as a function of total energy of the pulse train that actually exhibits the linear relation to the mass of erosion products. We established that the electrodes made of stainless steel and the electrodes made of graphite provide similar changes in water properties. An increase in pH is indicative of the progress of reactions that result in the formation of ОН⁻. Originality. The obtained experimental data prove a rapid and reliable change in the redox potential from positive to negative changes in the redox potential exponent can persist during ten days and even longer. The erosion products of electrodes can be removed from the treated water using the method of magnetic separation. Practical value. The "HYDRA" plant can be used as the electrochemical ideal mixing reactor of a discrete action with the removal of erosion products of the electrode using the method of magnetic separation.