Кафедра "Технологія кераміки, вогнетривів, скла та емалей"
Постійне посилання колекціїhttps://repository.kpi.kharkov.ua/handle/KhPI-Press/7480
Офіційний сайт кафедри http://web.kpi.kharkov.ua/ceramic
Кафедра "Технологія кераміки, вогнетривів, скла та емалей", первісна назва – кафедра силікатів, була створена в 1926 році в складі Харківського Хіміко-технологічного інституту.
Першим завідувачем кафедри (1926 – 1941 рр.) та засновником наукової школи був вчений зі світовим ім'ям, тричі Лауреат Державних премій, Заслужений діяч науки і техніки, академік АН УССР і член-кореспондент АН СССР, доктор технічних наук, професор Петро Петрович Будніков. Підготовка спеціалістів з силікатних технологій була започаткована в 1910 році на кафедрі мінеральної сировини під керівництвом академіка Єгора Івановича Орлова.
Кафедра входить до складу Навчально-наукового інституту хімічних технологій та інженерії Національного технічного університету "Харківський політехнічний інститут".
У складі науково-педагогічного колективу кафедри працюють: 5 докторів та 3 кандидата технічних наук; 4 співробітника мають звання професора, 3 – доцента.
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Документ New Heat-Insulating Dolomite Materials(Український державний університет залізничного транспорту, 2019) Taranenkova, V. V.; Shabanova, G. N.; Tymoshenko, I. S.; Korekian, P. Yu.Документ Binding properties of oxide compounds of special cements in interaction with water(Ukrainian State University of Chemical Technology, 2020) Taranenkova, V. V.; Pitak, Ya. N.; Shabanova, G. N.To synthesize special multimineral cements, it is necessary to have information concerning binding properties of individual phases being part of given cements. Despite numerous studies, there are not yet clear theoretical criteria to evaluate the behavior of various oxide compounds (if only qualitatively, not to mention quantitatively) with respect to their possible use in chemistry of special cements. Therefore, the development of corresponding quantitative dependences as well the ascertainment of the physical and chemical conditions determining the binding properties remain the actual task of chemistry of binding materials. Our study shows that a certain range of relative electronegativity values, where compounds under consideration reveal their binding properties, can be determined clearly by means of the concept of electronegativity. It is ascertained that some binary and ternary compounds (about 100) lie within a certain range of relative electronegativity, including those ones which binding properties have not been fully studied yet. Besides, the obtained data will allow selecting the most favorable conditions for compound hardening. Thus, in terms of our findings, the binding properties of oxide compounds and prospects of their application in special cement technology can be evaluated.Документ Alkali-earth element aluminates and chromites cement bonded refractory castables(The editorial committee of China's refractories, 2016) Shabanova, G. N.; Korohodska, A. M.This scientific paper gives the data of theoretical and experimental research done to solve the scientific and practical problem related to the establishment of theoretical basics and the development of the technology for the production of refractory castables of high strength, high refractoriness and hostile environment resistance on the basis of aluminates and chromites of alkaliearth elements due to the well-directed formation of the phase composition and the structure of clinker, cement stone and castables. The conceptual principles of the formation of such materials are based on the primary thermodynamically advantageous coexistence of the special-purpose combinations of phases in the subsolidus structure of the multicomponent subsystems of the oxide system (Mg, Ca, Sr, Ba)O – Al₂O₃ – Cr₂O₃. The obtained data allow for the development of highstrength refractory alumochromite cements and castables based on them. Specific features of the behavior of phase formation processes and the hydration of alumochromite cements, including the structure formation during the castable service have been studied.Документ Synthesis of specific binding on the base of the aluminate and chromate alkaline earth elements(2014) Korogodskaya, A. N.; Shabanova, G. N.Документ Refinement of the subsolidus structure of the four-component system Fe₂O₃–CaO–Al₂O₃–Cr₂O₃(Украинский государственный химико-технологический университет, 2019) Shabanova, G. N.; Korohodska, A. N.; Deviatova, N. B.The article describes the structure of the ternary subsystems of the four-component system CaO–Al₂O₃–Fe₂O₃–Cr₂O₃ . The calculations were performed with regard to three-component compounds. A tetrahedron of the four-component system CaO–Al₂O₃– Fe₂O₃–Cr₂O₃ has been plotted. The lengths of conodes and volumes of elementary tetrahedra were calculated. To study the relationship between elementary tetrahedra, a topological graph was constructed which allows using the obtained data in the study of oil-well cements based on this system. It has been established that the tetrahedron CaCr₂O₄–CaFe₂O₄–CaAl₂O₄–Ca₄Al₂Fe₂O₁₀ has the least degree of asymmetry (1.87), excluding some tetrahedra with simple oxides. The phases forming this tetrahedron most likely exist in the CaO– Al₂O₃–Cr₂O₃–Fe₂O₃ system. This will permit developing a sustainable process to fabricate oil-well cement materials based on the calcium aluminum-chromium cement without the use of special techniques to ensure high accuracy of dosing the initial components. In addition, when designing the compositions of binding materials, it is necessary to avoid the ternary compound localization area, because its coexistence with CaO will lead to the formation of portlandite in the cement clinker and to a significant decrease in the strength.Документ Modified alumina cement with high service properties(The editorial committee of China's refractories, 2016) Logvinkov, S. M.; Shabanova, G. N.; Korohodska, A. M.; Khrystych, E. V.This scientific paper gives consideration to the information on the contemporary structure of binary systems and three-component CaO – Al₂O₃ – ZrO₂ system required to select rational parameters for the synthesis of cementing agents. The production process of experimental clinker that has a Ca₇Al₆ZrO₁₈ composition has been described. The data of X-ray phase analysis and petrographic analysis of the experimental composition of special cement have been given and the reasons for availability of inappropriate phases have been analyzed. The processes of hydration hardening of the cement stone have been studied and the data of differential thermal analysis were used for the establishment of the hydration mechanism for basic crystal phases in the cement clinker composition. The differences in the hydration processes of experimental special cement were analyzed in comparison with known mechanisms. A possibility of the exploitation of special binder in contact with ZrO2 ( CaO–stabilized ) was tested using the specimens of fine concrete that were subjected to thermal treatment in different modes. The physical and mechanical properties of specimens and the mineralogical composition of concretes were given based on the data of X-ray analysis and the petrographic analysis. The cement additive was selected and its amount in the concrete composition was defined to slow-down the hardening and the mixture plasticization time. The relationships of physical and mechanical characteristics of concrete specimens were defined experimentally as a function of granulometric composition of the filler and thermal treatment temperature. The investigation data of corrosion resistance obtained using the static method were used to find out if experimental concretes can operate in contact with the steel-smelting alkaline slag.Документ Secondary resources recycling in building and refractory binders technology(Харківський національний університет будівництва та архітектури, 2016) Nagorniy, A. O.; Shabanova, G. N.; Korohodska, A. M.; Gaponova, O. O.The binders manufacture requires continuous expenditures of natural raw while there is a lack of relatively pure raw sources. Latest ten year analysis of limestone chemical content changing at the cement plants shows that limestone raw contains some impurities enabling to cause the long-time strength reducing. Thus, the traditional raw substitution along with the various industrial waste utilization problems is urgent in connection with a rising necessity to extend the raw base and to improve the ecological situation in Ukraine. Beside at the moment the million tons of waste are being accumulated and every year their amount rises.Документ Thermodynamic analysis of the possible existence of the ternary Вa₃СоAl₄O₁₀ compound in the ВаО–СоО–Аl₂O₃ system(Український державний хіміко-технологічний університет, 2020) Shabanova, G. N.; Korohodska, A. M.; Gamova, O. A.; Gaponova, H. A.; Levadnaya, S. V.The work was aimed at the thermodynamic estimation of the possible existence of ternary compound Вa₃СоAl₄O₁₀ in the BaO–CoO–Аl₂O₃ system. To this end, the composition of the expected ternary compound was calculated considering that this compound should be located in the CoAl₂O₄–Вa₃Аl₂O₆ conode. With reference to this, the temperature and the eutectic composition in the binary section of CoAl₂O₄–Вa₃Аl₂O₆ were estimated. The standard enthalpy of the formation of the above three-component compound, the standard entropy and the coefficients of the temperature dependence of the heat capacity were calculated. Using the method developed by Babushkin, the temperature dependence of the Gibbs energy for the formation of Вa₃СоAl₄O₁₀ compound was determined for the range of 800 to 2000 K. The probability of the Вa₃СоAl₄O₁₀ formation was evaluated both for its preparation both from pure aluminum, cobalt and barium oxides and from barium carbonate, aluminum and cobalt oxides. In addition, the probability of the Вa₃СоAl₄O₁₀ formation from binary compounds CoAl₂O₄ and Вa₃Аl₂O₆ was estimated. The possible formation of the ternary compound from Вa₃Аl₂O₆, BaAl₂O₄ and CoO was also considered, because the Вa₃СоAl₄O₁₀ compound is located in this triangle. The graphs of the change of Gibbs energy with temperature (800–2000 K) were plotted for all reactions. The obtained results showed that the formation of the ternary compound from barium, aluminum and cobalt oxides is more feasible from the standpoint of thermodynamics than from the binary compounds.Документ Heat-resistant concrete based on alumina cement from substandard raw material(Springer US, 2019) Vorozhbiyan, R. M.; Shabanova, G. N.; Korogodskaya, A. N.Results are provided for development of refractory concrete based on modified alumina cement using chemical industry waste. A quantitative ratio for mixed filler fractions, the effect of production factors on concrete strength, the dependence of its strength properties on form of filler, and solidification conditions are established. It is shown that with respect to physical mechanical and engineering properties the concretes developed is no worse than those existing in the market.With respect to all engineering properties this form of refractory product may be recommended as lining for high-temperature units.