Кафедра "Мікро- та наноелектроніка"

Постійне посилання колекціїhttps://repository.kpi.kharkov.ua/handle/KhPI-Press/2787

Офіційний сайт кафедри http://web.kpi.kharkov.ua/mne

Від 2022 року (НАКАЗ 31 ОД від 21.01.2022 року) кафедра має назву "Мікро- та наноелектроніка", первісна назва – "Фізичне матеріалознавство для електроніки та геліоенергетики". З 1.09.2024 р. (НАКАЗ 303 ОД від 28.08.2024 року ) кафедра "Радіоелектроніка" приєднана до кафедри "Мікро- та наноелектроніка"

Кафедра "Фізичне матеріалознавство для електроніки та геліоенергетики" була заснована у 1988 році з ініціативи Заслуженого діяча науки та техніки України, доктора фізико-математичних наук, профессора Бойка Бориса Тимофійовича.

За час існування кафедри в галузі електроніки на основі тонкоплівкових моделей були розроблені: нові технологічні методи виготовлення надійних конденсаторів на основі танталу та ніобію, елемент захисту електронних схем від імпульсних перепадів напруги, що не має світових аналогів, резистивний газовий датчик адсорбційно-напівпровідникового типу для аналізу навколишнього середовища тощо.

Кафедра входить до складу Навчально-наукового інституту комп'ютерного моделювання, прикладної фізики та математики Національного технічного університету "Харківський політехнічний інститут".

У складі науково-педагогічного колективу кафедри працюють: 1 доктор технічних наук, 4 кандидата технічних наук, 2 кандидата фізико-математичних наук; 3 співробітника мають звання доцента, 2 – старшого наукового співробітника, 1 – старшого дослідника.

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Amplitude-time characteristics of switching in thin films of cadmium telluride
(Сумський державний університет, 2018) Khrypunov, M. G.; Zaitsev, R. V.; Kudii, D. A.; Khrypunova, A. L.
The amplitudetime characteristics of switching in thin films of cadmium telluride were investigated when single impulses of 1 μs duration are applied. It has been experimentally established that with an increase in the thickness of the cadmium telluride layer from 3 μm to 8 μm, an increase in the operating threshold from 70 V to 105 V is observed. The maximum residual sample voltage varies from 12 V to 40 V, the minimum – from 5 V to 20 V. The switching time of the samples was no more than 2 nanoseconds; the interelectrode capacity of the samples was no more than 2 pF. All the test samples were operated without failure 20 times. The structural studies of cadmium telluride films by the method of X-ray diffractometry and scanning electron microscopy have made it possible to propose a mechanism for realizing the monostable switching of the columnar structure of cadmium telluride films oriented in the form of melted high-conductivity channels in grains oriented in the direction.
Effect of extraterrestrial solar UV radiation on structure and properties of ZnO films obtained by wet chemical methods
(Vasyl Stefanyk Precarpatian National University, 2019) Klochko, N. P.; Khrypunova, I. V.; Klepikova, K. S.; Petrushenko, S. I.; Kopach, V. R.; Zhadan, D. O.; Khrypunova, A. L.; Dukarov, S. V.; Lyubov, V. M.; Kirichenko, M. V.
Effect of Glow-discharge Hydrogen Plasma Treatment on Zinc Oxide Layers Prepared through Pulsed Electrochemical Deposition and via SILAR Method
(Sumy State University, 2019) Klochko, N. P.; Klepikova, K. S.; Petrushenko, S. I.; Nikitin, A. V.; Kopach, V. R.; Khrypunova, I. V.; Zhadan, D. O.; Dukarov, S. V.; Lyubov, V. M.; Khrypunova, A. L.
In this work, we investigated the effect of glow-discharge H₂⁺ plasma treatment on ZnO layers deposited on fluorine doped tin oxide (FTO) glass substrates through low temperature aqueous solution growth, namely, via a pulsed electrochemical deposition and by successive ionic layer adsorption and reaction (SILAR) technique. It is shown that the crystal structure, surface morphology, chemical composition and optical properties obtain some destructive changes after plasma processing due to the creation of oxygen vacancies Vo and H-related defects, and additionally, because of the zinc oxide etching by the glow-discharge H₂⁺ plasma through reduction of zinc oxide and evaporation of Zn from the surface. Neverthe-less, our investigations show quite good stability of the ZnO layers to the plasma-induced radiation and chemical impacts under high total H₂⁺ fluence received by every ZnO/FTO sample ~ 8·10¹⁸ cm⁻².
Flexible thermoelectric module based on zinc oxide thin film grown via SILAR
(2021) Klochko, N. P.; Klepikova, K. S.; Khrypunova, I. V.; Zhadan, D. O.; Petrushenko, S. I.; Kopach, V. R.; Dukarov, S. V.; Sukhov, V. M.; Kirichenko, M. V.; Khrypunova, A. L.
In this work, we used the low temperature solution growth Successive Ionic Layer Adsorption and Reaction (SILAR) for a deposition of the nanostructured undoped and indium doped (ZnO and ZnO:In) thin films on flexible polyimide (PI) substrates for their use as cheap non-toxic thermoelectric materials in the flexible thermoelectric modules of planar type to power up portable and wearable electronics and miniature devices. The use of a zincate solution in the SILAR method allows to obtain ZnO:In film, which after post-growth annealing at 300 ◦C has low resistivity ρ ≈ 0.02 Ω m, and high Seebeck coefficient 147 μV/K and thermoelectric power factor at near-room temperatures. As evidence of the operability of the manufactured films as the basis of the TE device, we have designed and tested experimental lightweight thin-film thermoelectric module. This TE module is able to produce specific output power 0.8 μW/m2 at ΔT = 50 K.
Influence of UV light of extraterrestrial solar irradiance on structure and properties of ZnO films prepared through pulsed electrochemical deposition and via SILAR method
(Сумський державний університет, 2018) Klochko, N. P.; Klepikova, K. S.; Petrushenko, S. I.; Kopach, V. R.; Khrypunov, G. S.; Zhadan, D. O.; Dukarov, S. V.; Lyubov, V. M.; Kirichenko, M. V.; Surovitskiy, S. V.; Khrypunova, A. L.
The investigations of effect of long-wave (UVA) and short-wave (UVC) ultraviolet light of extraterres-trial solar irradiance on the nanostructured zinc oxide arrays, which were grown by pulsed electrodeposition, as well as on the ZnO and ZnO:In films produced by Successive Ionic Layer Adsorption and Reaction technique (SILAR) confirmed their suitability as UVA-active photosensitive materials. The crystal structure, surface morphology, chemical composition and optical properties found no obvious significant destructive changes after UVC irradiation. However, we detected some irreversible changes in the nature of point defects under the influence of UVC, which affect the ZnO and ZnO:In resistivity, activation energy, photosensitivity and thermoelectrical properties.
Nanostructured Thermoelectric Thin Films Obtained by Wet Chemical Synthesis
(Sumy State University, 2017) Klochko, N. P.; Kopach, V. R.; Khrypunov, G. S.; Korsun, V. E.; Lyubov, V. M.; Otchenashko, О. N.; Zhadan, D. O.; Kirichenko, M. V.; Nikitin, V. О.; Maslak, M. O.; Khrypunova, A. L.
Nanostructured pristine lead sulfide and copper iodide semiconductor films as well as copper doped lead sulfide and iodine-enriched copper iodide layers were obtained on solid and flexible substrates via Chemical Bath Deposition (CBD) and Successive Ionic Layer Adsorption and Reaction (SILAR) methods. Crystal structures, optical, electric and thermoelectric properties of the layers have been studied. It was shown that the obtained films deposited on glass and mica substrates are smooth and continuous, have polycrystalline structures of the corresponding bulk semiconductors with grain sizes of several tens of nanometers. Investigations of the optical properties revealed, that their band gaps are characteristic for the corresponding bulk materials. All obtained semiconductor layers are p-type of conductivity. The resistivity of the lead sulphide films were reduced noticeably by means of their doping with copper. Iodination of the copper iodide films convert them into degenerate semiconductors. Investigations of the temperature dependent resistivity, the Seebeck coefficients and power factors confirmed that the obtained materials are promising for their use in thin-film solar thermoelectric generators with the aim of solar heat transforming into electricity.
Nanostructured ZnO and CuI Thin Films on Poly (Ethylene Terephthalate) Tapes for UV-Shielding Applications
(Sumy State University, 2020) Klochko, N. P.; Klepikova, K. S.; Zhadan, D. O.; Kopach, V. R.; Khrypunova, I. V.; Petrushenko, S. I.; Dukarov, S. V.; Lyubov, V. M.; Khrypunova, A. L.
In this work, we study a suitability for protection against terrestrial ultraviolet part of the solar spectrum of undoped and doped by indium zinc oxide thin nanostructured films, ZnO and ZnO:In, respectively, and cuprous iodide (CuI) films obtained via Successive Ionic Layer Adsorption and Reaction (SILAR) techniques on the lightweight low cost poly(ethylene terephthalate) (PET) flexible substrates. The film morphology is observed by scanning electron microscopy (SEM). Chemical compositions of the films are investigated by X-ray fluorescence (XRF) microanalysis. To research crystal structure we used X-ray diffraction (XRD) method. The UV-protection ability of the nanostructured thin films, PET tapes and samples consisting of the PET substrates and the films deposited on them by the SILAR method has been evaluated on the base of their optical properties in accordance with an international standard ISO 2443:2012(E) “Determination of sunscreen UVA photoprotection in vitro”. According to the research, nanostructured ZnO, ZnO:In and CuI thin films made by the cheap, affordable, and suitable for mass production SILAR method on thin flexible cheap PET substrates have been proposed as a new material for UV-shielding applications. In accordance with an international standard ISO 2443:2012(E), UV-protection ability of the samples consisting of the PET substrates and the films deposited on them by the SILAR method fits the category “excellent” (50+). The best low cost flexible and lightweight UV shielding material turned out to be that consisted from ZnO:In film and PET substrate, the sun protection factor of which equals 157.
Nanostructured ZnO arrays fabricated via pulsed electrodeposition and coated with Ag nanoparticles for ultraviolet photosensors
(Сумський державний університет, 2018) Klochko, N. P.; Klepikova, K. S.; Petrushenko, S. I.; Kopach, V. R.; Khrypunov, G. S.; Korsun, V. E.; Lyubov, V. M.; Kirichenko, M. V.; Dukarov, S. V.; Khrypunova, A. L.
Nanostructured one-dimensional (1-D) ZnO arrays fabricated via pulsed electrodeposition and coated with Ag nanoparticles are researched with the aim of their using in the ultraviolet (UV) photosensors. The results of the crystal structure investigations showed that the pulsed electrodeposited zinc oxide arrays are polycrystalline in nature and matching with hexagonal wurtzite modification of ZnO. To enhance its UV photosensitivity, the silver nanoparticles (AgNPs) with different shape and an average size of 60 nm, as well as 300-500 nm long Ag nanorods with ~30 nm diameter, are precipitated mainly on the (002), (101) and (100) ZnO planes. Study of electrical properties and electronic parameters of the 1-D ZnO and Ag/ZnO nanocomposites using a current-voltage and capacity-voltage characteristics identified the important role of the high double Schottky barriers at the ZnO intergrain boundaries for the creation of great UV photo-sensitivity. It is proved that through monitoring the amount of AgNPs on the ZnO surface the electrical properties and electronic parameters of the Ag/ZnO nanocomposites, and consequently, the output parameters of the UV photosensors can be controlled.
Nanostructured СuI thin films on biodegradable nanocellulose flexible substrates for UV-shielding applications
(Kamianets-Podіlskyi National Ivan Ohiienko University, 2020) Klochko, N. P.; Barbash, V. A.; Klepikova, K. S.; Kopach, V. R.; Yashchenko, O. V.; Zhadan, D. O.; Petrushenko, S. I.; Dukarov, S. V.; Sukhov, V. M.; Khrypunova, A. L.
Physical and technological foundations of the "Chloride" treatment of cadmium telluride layers for thin-film photoelectric converters
(Сумський державний університет, 2018) Kudii, D. A.; Khrypunov, M. G.; Zaitsev, R. V.; Khrypunova, A. L.
The process of deposition of cadmium chloride films during the "chloride" treatment of cadmium telluride base layers for thin-film photoelectric converters (PEC) was studied. It is established that to ensure the reproducibility of the thickness and phase composition of cadmium chloride films, it is necessary to take into account the high hygroscopicity of this material. It is shown that the optimal growth rate of cadmium chloride films is 0.1 μm perminute. At high growth rates, cadmium chloride particulates are deposited on the surface of the CdTe layer base, which causes shunting of the PEC during the "chloride" treat-ment. It is determined that after the "chloride" treatment of CdTe layers, a coarse-grained structure is observed, which is predominantly oriented in the thermodynamic equilibrium direction. In this case, the average grain size increases to 5 μm. It is shown that when performing a "chloride" treatment, the optimum purity of cadmium chloride layers is 98 %, which is due to the doping of CdTe with copper atoms. The disadvantage of copper with the use of more pure cadmium chloride reduces the efficiency of the PEC due to the increase in the series resistivity and the decrease in the photocurrent density. It has been experimentally determined that the optimum thickness of cadmium chloride during the "chloride" treatment and the efficiency of the PEC obtained at the same time depends on the substrate used. Thus, for the ITO/CdS/CdTe/Cu/Au PEC, the optimum thickness of cadmium chloride is 0.40 μm, the efficiency is 9.6 %, and for the NaCl/ITO/CdS/CdTe/Cu/Au PEC – 0.10 μm and 6.4 %, respectively.
Wettability of the cotton and polyester tissues coated by nanostructured indium-doped zinc oxide layers
(Ivan Franko National University of Lviv, 2020) Klochko, N. P.; Khrypunova, I. V.; Klepikova, K. S.; Kopach, V. R.; Zhadan, D. O.; Petrushenko, S. I.; Dukarov, S. V.; Lyubov, V. M.; Kirichenko, M. V.; Khrypunova, A. L.