Кафедра "Хімічна техніка та промислова екологія"

Постійне посилання колекціїhttps://repository.kpi.kharkov.ua/handle/KhPI-Press/7479

Офіційний сайт кафедри http://web.kpi.kharkov.ua/htpe

Від 1999 року кафедра має назву "Хімічна техніка та промислова екологія", попередня назва – кафедра механічного устаткування хімічних виробництв.

Кафедра механічного устаткування хімічних виробництв була організована 18 жовтня 1946 року у складі факультету технології неорганічних речовин Харківського хіміко-технологічного інституту. Становлення кафедри пов’язане з іменами доцентів Георгія Веніаміновича Петрова, М. Ковальова, Абрама Натановича Цейтліна, Анісіма Рудольфовича (Рувиновича) Ястребнецького . У 1960 році на базі кафедри створено Факультет хімічного машинобудування.

Кафедра входить до складу Навчально-наукового інституту механічної інженерії і транспорту Національного технічного університету "Харківський політехнічний інститут".

У складі науково-педагогічного колективу кафедри працюють: 2 доктора та 14 кандидатів технічних наук, 4 доктора філософії; 3 співробітника мають звання професора, 12 – доцента.

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2022 - 20242

Налаштування

ORCID: search.filters.orcid.https://orcid.org/0000-0002-3061-3313

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  • Ескіз
    Документ
    Identification of the oxidation and hydrolysis products content influence on the rapeseed oil oxidation induction period
    (Technology center PC, 2024) Stankevych, Serhii; Gorbunov, Kostiantyn; Zabrodina, Inna; Popov, Mykola; Kalyna, Viktoriia; Novozhylova, Tetiana; Falalieieva, Tetiana; Ovsiannikova, Tetiana; Ponomarova, Maryna; Zolotarov, Andrii
    The object of the study is the dependence of the induction period of rapeseed oil on the content of oxidation and hydrolysis products. A feature of the work is determining the approximation dependence of the induction period of accelerated oxidation of refined rapeseed oil on the content of primary oxidation products and free fatty acids. This is useful when predicting the shelf life of refined rapeseed oil. It was determined that both factors negatively affect the oxidation stability of refined rapeseed oil. An increase in the peroxide value decreases the induction period of model oil samples by 32.8512 units for each additional mmol ½ O/kg. In turn, increasing the acid value of oil samples reduces the induction period by 19.8424 units for each additional mg KOH/g. Different oxidation dynamics of model samples of refined rapeseed oil with tocopherol were revealed, depending on the concentration of primary oxidation and hydrolysis products. The obtained data are explained by the fact that the primary lipid oxidation products are unstable and quickly decompose to form free radicals. These radicals initiate further lipid oxidation, resulting in reduced oil quality. In addition, free fatty acids are more reactive than triglycerides and are more easily oxidized. A feature of the obtained results is the possibility of modeling processes that affect the oxidation stability of refined rapeseed oil. From a practical point of view, the research results allow initiating measures to maintain the safety of oil-containing food products based on refined rapeseed oil. An applied aspect of using the scientific results is the possibility of rationalizing the storage conditions of refined rapeseed oil to maximize its shelf life and increase competitiveness.
  • Ескіз
    Публікація
    Improvement of the technology of fatty acids obtaining from oil and fat production waste
    (PC Technology center, 2022) Kalyna, Viktoriia; Stankevych, Serhii; Myronenko, Liliia; Hrechko, Andrii; Bogatov, Oleg; Bragin, Oleksandr; Romanov, Oleksii; Ogurtsov, Yuriy; Semenov, Evgeny; Filenko, Olesya
    Fatty acids are an important component in the pharmaceutical, food, chemical industries. The production of various types of products requires a certain purity and quality of fatty acids. To obtain these compounds, it is promising to use soapstocks, which are waste products of alkaline refining of oils. The peculiarity of the work lies in determining the effect of the process parameters of soapstock decomposition with sulfuric acid on the saponification number, which is an important production characteristic of fatty acids. The study used sunflower soapstock according to DSTU 5033 (CAS 68952-95-4) with a mass fraction of total fat of 69.5 %, fatty acids – 64.5 %. The soapstock was treated with a sulfuric acid solution at a temperature of 90 °C, the process duration was 40 min. Rational parameters of soapstock treatment were determined: concentration of sulfuric acid in the reaction mass is 80 %, concentration of an aqueous solution of sulfuric acid – 50 %. In the experiment interval, the settling duration of the reaction mass does not affect the saponification number of fatty acids. The settling time of 1 hour is effective for the isolation of fatty acids. Under these conditions, the saponification number of fatty acids was 186.4 mg KOH/g. The acids correspond to fatty acids of the first grade according to DSTU 4860 (CAS 61788-66-7): mass fraction of moisture and volatile substances – 1.2 %, mass fraction of total fat – 97.5 %, cleavage depth – 95.0 % oleic acid. The obtained data allow rational and most efficient use of the reagent – sulfuric acid. The results of the work make it possible to reduce the duration of fatty acids obtaining from soapstocks, since the efficiency of the process with the minimum duration of mass settling has been confirmed. The improved technology of soapstock decomposition makes it possible to obtain a valuable product – high-quality fatty acids under rational conditions.