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Документ Structural engineering and functional properties of vacuum-arc coatings of high-entropy (TiZrNbVHf)N and (TiZrNbVHfTa)N alloys nitrides(Institute for Single Crystals, 2019) Sobol, O. V.; Dur, Osman; Postelnyk, A. A.The effect of nitrogen pressure during the deposition of vacuum-arc (TiZrNbVHf)N and (TiZrNbVHfTa)N coatings on their phase-structural state, substructure and resistance to abrasive wear was investigated. It was established that in multi-element (based on high-entropy alloys) (TiZrNbVHf)N and (TiZrNbVHfTa)N coatings obtained in a nitrogen atmosphere in the range of nitrogen pressures PN = 2.5 ·10-4-4.5 ·10-3 Torr, a single-phase state is formed (based on cubic crystal lattice of structural type NaCl). The use of a multi-element composition with a single-phase state with a cubic lattice allows for (Ti-V-Zr-Nb-Hf-Ta)N coatings to achieve high microstrain values (up to 1.2 %) at low deposition pressure. It was found that high-entropy nitride coatings with low abrasive wear are characterized by a crystallite grain size of less than 50 nm, the absence or low level of texture perfection [111], and the presence of a rather high microstrain in crystallites (reaching 1.2 %). The reasons for the observed changes in the structural state and substructure of multi-element nitride coatings and their effect on abrasive resistance are discussed.Документ Influence of Bias Potential Magnitude on Structural Engineering of ZrN-Based Vacuum-Arc Coatings(Vasyl Stefanyk Precarpathian National University, 2021) Sobol, O. V.; Postelnyk, H. O.; Pinchuk, N. V.; Meylekhov, A. A.; Zhadko, M. A.; Andreev, A. A.; Stolbovoy, V. A.The creation of the scientific foundations for the structural engineering of ultrathin nanolayers in multilayer nanocomposites is the basis of modern technologies for the formation of materials with unique functional properties. It is shown that an increase in the negative bias potential (from -70 to -220 V) during the formation of vacuum-arc nanocomposites based on ZrN makes it possible not only to control the preferred orientation of crystallites and substructural characteristics, but also changes the conditions for conjugation of crystal lattices in ultrafine (about 8 nm) nanolayers.Документ Formation of Superhard State of the TiZrHfNbTaYN Vacuum–Arc High-Entropy Coating(Allerton Press, Inc., 2018) Beresnev, V. M.; Sobol, O. V.; Andreev, A. A.; Gorban, V. F.; Klimenko, S. A.; Litovchenko, S. V.; Kovteba, D. V.; Meilekhov, A. A.; Postelnyk, A. A.; Nemchenko, U. S.; Novikov, V. Yu.; Maziilin, B. A.Complex studies of the formation of the superhard state in the TiZrHfNbTaYN vacuum-arc high-entropy coating were carried out. Based on the approach of the structural surface engineering, the regularities of the formation of the triads composition–structure–physico-mechanical properties depending on the supplied potential displacement are established. It is shown that the increase of Ub at the formation of a coating leads to a decrease of the relative content of a light (Ti) and increase of a heavy (Ta, Hf) metal components, which is determined by radiationally stimulated processes in a near surface region at the deposition. The formation of the single-phase state (based on the fcc of metal lattice) in the range Ubfrom –50 to –250 V and revealed the formation of the preferred orientation of the crystallites with the axis [111], which is perpendicular to the growth plane. The increase of the perfection of the texture with the [111] axis with increasing Ub is accompanied with an increase of the coatings hardness, which makes it possible to achieve the superhard state (H = 40.2 GPa) at Ub = –250 V.Документ The Use of Negative Bias Potential for Structural Engineering of Vacuum-Arc Nitride Coatings Based on FeCoNiCuAlCrV High-Entropy Alloy(Sumy State University, 2018) Sobol, O. V.; Andreev, A. A.; Gorban, V. F.; Meylekhov, A. A.; Postelnуk, A. A.; Stolbovoy, V. A.; Zvyagolskiy, A. V.The effect of negative bias potential (Ub = – 40, – 110, and – 200 V) upon the deposition of multielement coatings on their composition, structure, and mechanical properties was studied. It is shown that when using a high-entropy multielement (of 7 elements) FeCoNiCuAlCrV alloy, it is possible to obtain a single-phase nitride (FeCoNiCuAlCrV)N. Nitride has an fcc crystal lattice (structural type NaCl). It has been established that with an increase in Ub in the structural state occurs transition from practically nontextured (polycrystalline) to the preferential orientation of the growth of crystallites with the [111] texture axis (at Ub = – 110 V) and [110] (at Ub = – 200 V). This is accompanied by a decrease in the lattice period, as well as a decrease in hardness and modulus of elasticity. For coatings (FeCoNiCuAlCrV) N, the highest hardness of 38 GPa is achieved by using the smallest (– 40 V) bias potential during the deposition process. It is shown that to achieve high hardness at high Ub it is necessary to increase the content in the highentropy alloy of elements with high nitride-forming ability.Документ Influence of the Bias Potential and the Pressure of the Nitrogen Atmosphere on the Structure and Properties of Vacuum-arc Coatings Based on the AlCrTiZrNbV High-entropy Alloy(Sumy State University, 2018) Sobol, O. V.; Andreev, A. A.; Gorban, V. F.; Postelnyk, A. A.; Stolbovoy, V. A.; Zvyagolskiy, A. V.The effect of the constant bias potential (Ub) supplied to the substrate upon condensation and pressure of the nitrogen atmosphere (PN) on the elemental composition, growth morphology, texture, and physical-mechanical characteristics of vacuum-arc (AlCrTiVZrNb)Nx coatings is studied. It is established that with increasing Ub from – 110V to – 200V, the axis of preferential growth of crystallites of the fcc phase from [100] to [110] changes. Such a change is accompanied by a decrease in the hardness (H) and the ratio H/E (where E is the modulus of elasticity). The conditions for the formation of the preferential orientation of the crystallites (axial texture) of vacuum-arc (AlCrTiVZrNb)Nx coatings and the influence of texture on mechanical properties are discussed. It was established that the change in PN in the range Torr basically allows to vary the degree of filling of the coating with nitrogen atoms. Based on the revealed regularities, the conditions for achieving high hardness for vacuum-arc coatings of nitrides AlCrTiVZrNb high-entropy alloy are substantiated. Because of the presence in the alloy of elements with a relatively low heat of nitride formation, in order to achieve high hardness, it is necessary to use deposition conditions with relatively low energy of bombarding atoms. The use of a low Ub = –110 V at the highest pressure Torr allows achieving an superhard state with a hardness of 44 GPa.Документ Structural Engineering and Mechanical Properties of (Ti-V-Zr-Nb-Hf-Ta)N Coatings Obtained at Different Pressures(Сумський державний університет, 2019) Sobol, O. V.; Andreev, A. A.; Postelnyk, H. O.; Meylekhov, A. A.; Sagaidashnikov, Yu. Ye.; Stolbovoy, V. A.; Yevtushenko, N. S.; Syrenko, T. O.; Kraievska, Zh. V.; Zvyagolskiy, A. V.Effect of pressure of the reaction gas on the texture, structural stress state and mechanical properties (hardness and resistance to abrasive wear) in vacuum-arc coatings based on Ti-V-Zr-Nb-Hf-Ta nitrides of high entropy alloys were investigated in this work. At a bias potential of – 200V, an increase in nitrogen pressure during deposition from 2.5·10⁻⁴ to 4.5·10⁻³ Torr leads to an increase in the content of nitrogen atoms in the coating, and the formation of a bittexture state [111] + [311] is established. The formation of a biaxial texture occurs due to the presence in alloys of atoms with very different masses (Ti, V and Hf, Ta). The use of a multi-element composition in a single-phase state with a simple cubic lattice allows to achieve high values of microstrain (up to 1.4 %) with a low deposition pressure. It is determined that the increase of nitrogen pressure during deposition leads to an increase in macrostresses. The highest hardness of 53 GPa is achieved in coatings obtained at a pressure of 2·10⁻³ Torr. It has been established that coatings with high resistance to abrasive wear are found to be: crystallite grain size 12-25 nm, absent of texture (or a low level of texture perfection), and also rather high microstrain in crystallites.